CH₃OC₆H₄CH₂(C₅H₅N)Co((CH₃CNO)2H)((C₆H₅CNO)2H)

Base Information

• Chemical Name: CH₃OC₆H₄CH₂(C₅H₅N)Co((CH₃CNO)2H)((C₆H₅CNO)2H)
• CAS No.: 352354-01-9
• Molecular Formula: C₃₁H₃₂CoN₅O₅
• Molecular Weight: 613.619
• Mol file: 352354-01-9.mol

Synonyms:

Chemical Property of CH₃OC₆H₄CH₂(C₅H₅N)Co((CH₃CNO)2H)((C₆H₅CNO)2H)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of CH₃OC₆H₄CH₂(C₅H₅N)Co((CH₃CNO)2H)((C₆H₅CNO)2H)

There total 1 articles about CH₃OC₆H₄CH₂(C₅H₅N)Co((CH₃CNO)2H)((C₆H₅CNO)2H) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 31.0%

trans-bis(dimethylglyoximato)(pyridine)chlorocobalt(III) + trans-bis(diphenylglyoximato)(pyridine)chlorocobalt(III) + p-methoxybenzyl chloride (824-94-2) → CH3OC6H4CH2(C5H5N)Co((CH3CNO)2H)2 (42194-65-0) + CH3OC6H4CH2(C5H5N)Co((CH3CNO)2H)((C6H5CNO)2H) (352354-01-9) + CH3OC6H4CH2(C5H5N)Co((C6H5CNO)2H)2 (217814-35-2)

Guidance literature:

With NaOH; NaBH₄; In methanol; water; addn. of aq. soln. of NaOH to a suspn. of cobalt complexes in CH3OH, purging with argon for 15 min, cooling to 0°C, addn. of a soln. of NaBH4 in CH3OH, stirring for 10 min, addn. of a soln. of ligand in CH3OH,stirring for 3 h in the dark; pouring into water, filtration, drying, column chromy (SiO2, ethylacetate/CHCl3);

DOI:10.1016/S0022-328X(01)00731-8

upstream raw materials:

p-methoxybenzyl chloride