NiI(C₆H₅B(CH₂P(C₆H₅)2)3)

Base Information

Chemical Name:NiI(C₆H₅B(CH₂P(C₆H₅)2)3)
CAS No.:741735-76-2
Molecular Formula:C₄₅H₄₁BINiP₃
Molecular Weight:871.147
Hs Code.:

NiI(C<sub>6</sub>H<sub>5</sub>B(CH<sub>2</sub>P(C<sub>6</sub>H<sub>5</sub>)2)3)

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Chemical Property of NiI(C₆H₅B(CH₂P(C₆H₅)2)3)

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Technology Process of NiI(C₆H₅B(CH₂P(C₆H₅)2)3)

There total 2 articles about NiI(C₆H₅B(CH₂P(C₆H₅)2)3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 13462-90-3
nickel(II) iodide

: 388110-49-4
tallium (diphenylphosphinomethyl)phenylborate

: 741735-76-2
NiI(C₆H₅B(CH₂P(C₆H₅)2)3)

Guidance literature:: In benzene; byproducts: TlCl; under N2; benzene soln. of Tl-complex was added dropwise to suspn. of NiI2 in benzene, stirred at room temp. for 24 h; filtered, concd. under reduced pressure, filtered, vapor diffusion of petroleum ether; elem. anal.;
DOI:10.1021/ic049936p

Reference yield: 81.0%

: 741735-75-1
NiCl(C₆H₅B(CH₂P(C₆H₅)2)3)

: 741736-15-2
Tl⁽¹⁺⁾*SC₆H₄C(CH₃)3^(1-)=Tl(SC(CH₃)3C₆H₄)

: 741735-76-2
NiI(C₆H₅B(CH₂P(C₆H₅)2)3)

Guidance literature:: In tetrahydrofuran; byproducts: TlCl; under N2; THF soln. of Tl-salt was added dropwise to suspn. of Ni-complex in THF, stirred for 3 h; concd. under reduced pressure, extd. with benzene, filtered, vapor diffusion of petroleum ether into benzene soln.; elem. anal.;
DOI:10.1021/ic049936p

Reference yield: 42.0%

: 741735-76-2
NiI(C₆H₅B(CH₂P(C₆H₅)2)3)

: [PhB(CH2PPh2)3]Ni(η2-CH2PPh2)

Guidance literature:: With Na/Hg; In tetrahydrofuran; under N2; THF soln. of Ni-complex was added dropwise to Na/Hg in THF, stirred for 24 h; decanted, removed under reduced pressure, extd. with toluene, filtered, stored at -40°C overnight;
DOI:10.1021/ic049936p