2'-phenylsulfonyl-γ-tocotrienyl benzyl ether

Base Information

Chemical Name:2'-phenylsulfonyl-γ-tocotrienyl benzyl ether
CAS No.:951404-43-6
Molecular Formula:C₄₁H₅₂O₄S
Molecular Weight:640.927
Hs Code.:

Synonyms:

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Chemical Property of 2'-phenylsulfonyl-γ-tocotrienyl benzyl ether

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Technology Process of 2'-phenylsulfonyl-γ-tocotrienyl benzyl ether

There total 9 articles about 2'-phenylsulfonyl-γ-tocotrienyl benzyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 608-43-5
2,3-dimethyl-1,4-dihydroxybenzene

: 951404-43-6
2'-phenylsulfonyl-γ-tocotrienyl benzyl ether

Guidance literature:: Multi-step reaction with 8 steps

1.1: pyridine / benzene / 1 h / 0 °C

2.1: 80 percent / dibutylamine; acetic acid / 23 h / Heating

3.1: 99 percent / lithium aluminium hydride / diethyl ether

4.1: PS-30 lipase on hyflosupercell / various solvent(s) / 5 h / 20 °C

4.2: aq. LiOH / methanol; tetrahydrofuran / 0.33 h

4.3: PS-30 lipase on hyflosupercell / various solvent(s) / 5 h / 20 °C

5.1: aq. LiOH / tetrahydrofuran; methanol / 0.33 h

6.1: 71 percent / K₂CO₃ / dimethylformamide / 12 h

7.1: 95 percent / pyridine / 2 h

8.1: n-butyllithium; HMPA / tetrahydrofuran; hexane / 0.75 h / -78 °C

8.2: 63 percent / tetrahydrofuran; hexane / 2 h / -78 - 20 °C

With pyridine; N,N,N,N,N,N-hexamethylphosphoric triamide; lithium hydroxide; lithium aluminium tetrahydride; n-butyllithium; potassium carbonate; dibutylamine; acetic acid; In tetrahydrofuran; methanol; diethyl ether; hexane; N,N-dimethyl-formamide; benzene;
DOI:10.1021/jo0705418

Reference yield:

: 951404-32-3
2,7,8-trimethyl-6-hydroxychroman-2-methanol

: 951404-43-6
2'-phenylsulfonyl-γ-tocotrienyl benzyl ether

Guidance literature:: Multi-step reaction with 5 steps

1.1: PS-30 lipase on hyflosupercell / various solvent(s) / 5 h / 20 °C

1.2: aq. LiOH / methanol; tetrahydrofuran / 0.33 h

1.3: PS-30 lipase on hyflosupercell / various solvent(s) / 5 h / 20 °C

2.1: aq. LiOH / tetrahydrofuran; methanol / 0.33 h

3.1: 71 percent / K₂CO₃ / dimethylformamide / 12 h

4.1: 95 percent / pyridine / 2 h

5.1: n-butyllithium; HMPA / tetrahydrofuran; hexane / 0.75 h / -78 °C

5.2: 63 percent / tetrahydrofuran; hexane / 2 h / -78 - 20 °C

With pyridine; N,N,N,N,N,N-hexamethylphosphoric triamide; lithium hydroxide; n-butyllithium; potassium carbonate; In tetrahydrofuran; methanol; hexane; N,N-dimethyl-formamide;
DOI:10.1021/jo0705418

Reference yield:

: 951404-30-1
methyl 2,7,8-trimethyl-6-benzoyloxychroman-2-carboxylate

: 951404-43-6
2'-phenylsulfonyl-γ-tocotrienyl benzyl ether

Guidance literature:: Multi-step reaction with 6 steps

1.1: 99 percent / lithium aluminium hydride / diethyl ether

2.1: PS-30 lipase on hyflosupercell / various solvent(s) / 5 h / 20 °C

2.2: aq. LiOH / methanol; tetrahydrofuran / 0.33 h

2.3: PS-30 lipase on hyflosupercell / various solvent(s) / 5 h / 20 °C

3.1: aq. LiOH / tetrahydrofuran; methanol / 0.33 h

4.1: 71 percent / K₂CO₃ / dimethylformamide / 12 h

5.1: 95 percent / pyridine / 2 h

6.1: n-butyllithium; HMPA / tetrahydrofuran; hexane / 0.75 h / -78 °C

6.2: 63 percent / tetrahydrofuran; hexane / 2 h / -78 - 20 °C

With pyridine; N,N,N,N,N,N-hexamethylphosphoric triamide; lithium hydroxide; lithium aluminium tetrahydride; n-butyllithium; potassium carbonate; In tetrahydrofuran; methanol; diethyl ether; hexane; N,N-dimethyl-formamide;
DOI:10.1021/jo0705418