1,14-bisformyl-5,10-bis{3,5-bis[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]phenyl}tripyrrane

Base Information

Chemical Name:1,14-bisformyl-5,10-bis{3,5-bis[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]phenyl}tripyrrane
CAS No.:889361-06-2
Molecular Formula:C₅₆H₇₉N₃O₁₈
Molecular Weight:1082.25
Hs Code.:

Synonyms:

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Chemical Property of 1,14-bisformyl-5,10-bis{3,5-bis[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]phenyl}tripyrrane

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Technology Process of 1,14-bisformyl-5,10-bis{3,5-bis[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]phenyl}tripyrrane

There total 1 articles about 1,14-bisformyl-5,10-bis{3,5-bis[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]phenyl}tripyrrane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 68-12-2,33513-42-7
N,N-dimethyl-formamide

: 651323-18-1
5,10-bis{3,5-bis[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]phenyl}tripyrrane

: 889361-06-2
1,14-bisformyl-5,10-bis{3,5-bis[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]phenyl}tripyrrane

Guidance literature:: N,N-dimethyl-formamide; 5,10-bis{3,5-bis[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]phenyl}tripyrrane; With trichlorophosphate; at 20 ℃; for 1.5h;

With sodium hydroxide; at 80 - 90 ℃; for 8h;
DOI:10.1039/b515636j

Reference yield: 26.0%

: 889361-06-2
1,14-bisformyl-5,10-bis{3,5-bis[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]phenyl}tripyrrane

: 14432-01-0,15280-53-2,79464-08-7,100587-93-7,138481-01-3
gadolinium(III) acetate tetrahydrate

: 95-54-5
1,2-diamino-benzene

: Gd⁽³⁺⁾*N₅C₂₂H₁₂(C₆H₃(O(CH₂CH₂O)3CH₃)2)2^(1-)*2O₂CCH₃^(1-)=(Gd(N₅C₂₂H₁₂(C₆H₃(O(CH₂CH₂O)3CH₃)2)2))(O₂CCH₃)2

Guidance literature:: With hydrogenchloride; air; triethylamine; In methanol; water; under Ar; 37% HCl added at room temp. to soln. of dialdehyde and C6H4(NH2)2 in MeOH; heated at reflux for 10 h; Gd salt and Et3N added; stirred at reflux for 24 h in air; cooled to room temp.; solvent removed under reduced pressure; dried in vac. for several h; column chromd. (neutral alumina, MeOH-CH2Cl2); green fractions washed (aq. NaOAc); org. soln. concd.; purified using tC18 cartridge column;
DOI:10.1039/b515636j

Reference yield: 23.0%

: 889361-06-2
1,14-bisformyl-5,10-bis{3,5-bis[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]phenyl}tripyrrane

: 771-97-1
2,3-Diaminonaphthalene

: 14432-01-0,15280-53-2,79464-08-7,100587-93-7,138481-01-3
gadolinium(III) acetate tetrahydrate

: Gd⁽³⁺⁾*N₅C₂₆H₁₄(C₆H₃(O(CH₂CH₂O)3CH₃)2)2^(1-)*2O₂CCH₃^(1-)=(Gd(N₅C₂₆H₁₄(C₆H₃(O(CH₂CH₂O)3CH₃)2)2))(O₂CCH₃)2

Guidance literature:: With hydrogenchloride; 1,8-diaza-bicyclo[5.4.0]undecene; triethylamine; In methanol; water; under Ar; 37% HCl added at room temp. to soln. of dialdehyde and diaminonaphthalene in MeOH; heated at reflux for 10 h; Gd salt, Et3N and DBU added; stirred at reflux for 24 h in air; cooled to room temp.; solvent removed under reduced pressure; dried in vac. for several h; column chromd. (neutral alumina, MeOH-CH2Cl2); green fractions washed (aq. NaOAc); org. layer collected; solvent evapd. under reduced pressure; purified using tC18 cartridge column;
DOI:10.1039/b515636j