anti-1,8-bis(3,3'-(3,5-dimethylphenyl)-9,9'-diacridyl)naphthalene

Base Information

• Chemical Name: anti-1,8-bis(3,3'-(3,5-dimethylphenyl)-9,9'-diacridyl)naphthalene
• CAS No.: 807610-46-4
• Molecular Formula: C₅₂H₃₈N₂
• Molecular Weight: 690.887
• Mol file: 807610-46-4.mol

Synonyms:

Chemical Property of anti-1,8-bis(3,3'-(3,5-dimethylphenyl)-9,9'-diacridyl)naphthalene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of anti-1,8-bis(3,3'-(3,5-dimethylphenyl)-9,9'-diacridyl)naphthalene

There total 7 articles about anti-1,8-bis(3,3'-(3,5-dimethylphenyl)-9,9'-diacridyl)naphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

3-(3,5'-dimethylphenyl)-9-tri-n-butylstannylacridine + 1,8-dibromonaphthalene (17135-74-9) → anti-1,8-bis(3,3'-(3,5-dimethylphenyl)-9,9'-diacridyl)naphthalene (783333-49-3,807610-46-4,807610-47-5,807610-48-6,807610-49-7)

Guidance literature:

1,8-dibromonaphthalene; With tetrakis(triphenylphosphine) palladium⁽⁰⁾; copper(II) oxide; In N,N-dimethyl-formamide; at 130 ℃; for 0.0833333h; Inert atmosphere;

3-(3,5'-dimethylphenyl)-9-tri-n-butylstannylacridine; In N,N-dimethyl-formamide; at 130 ℃; for 40h; Inert atmosphere;

DOI:10.1021/jo300738s

Reference yield: 66.0%

1,8-dibromonaphthalene (17135-74-9) + 3-(3',5'-dimethylphenyl)-9-trimethylstannylacridine (783325-79-1) → anti-1,8-bis(3,3'-(3,5-dimethylphenyl)-9,9'-diacridyl)naphthalene (783333-49-3,807610-46-4,807610-47-5,807610-48-6,807610-49-7)

Guidance literature:

With copper(II) oxide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In N,N-dimethyl-formamide; at 130 ℃; for 20h;

DOI:10.1021/jo0600353

Reference yield:

1,8-dibromonaphthalene (17135-74-9) + 9-bromo-3-(3',5'-dimethylphenyl)acridine (783325-77-9) → anti-1,8-bis(3,3'-(3,5-dimethylphenyl)-9,9'-diacridyl)naphthalene (783333-49-3,807610-46-4,807610-47-5,807610-48-6,807610-49-7)

Guidance literature:

9-bromo-3-(3',5'-dimethylphenyl)acridine; With n-butyllithium; In tetrahydrofuran; diethyl ether; hexane; at -78 ℃; for 1h;

With tributyltin chloride; In tetrahydrofuran; diethyl ether; hexane; at 20 ℃; for 18h;

1,8-dibromonaphthalene; With tetrakis(triphenylphosphine) palladium⁽⁰⁾; copper(II) oxide; In N,N-dimethyl-formamide; at 130 ℃; for 20h;

DOI:10.1016/j.tetlet.2006.09.012

upstream raw materials:

1,8-dibromonaphthalene

3-(3',5'-dimethylphenyl)-9-trimethylstannylacridine

9-bromo-3-(3',5'-dimethylphenyl)acridine

4-(3',5'-dimethylphenyl)-2-chlorobenzoic acid