tricarbonyl(η4-2,5-diphenylthiophene dioxide)iron

Base Information

• Chemical Name: tricarbonyl(η4-2,5-diphenylthiophene dioxide)iron
• CAS No.: 132080-68-3
• Molecular Formula: C₁₉H₁₂FeO₅S
• Molecular Weight: 408.214
• Mol file: 132080-68-3.mol

Synonyms:

Chemical Property of tricarbonyl(η4-2,5-diphenylthiophene dioxide)iron

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tricarbonyl(η4-2,5-diphenylthiophene dioxide)iron

There total 2 articles about tricarbonyl(η4-2,5-diphenylthiophene dioxide)iron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

iron pentacarbonyl (13463-40-6,37220-42-1) + 2,5-bis(phenyl)-thiophene-1,1-dioxide (51092-02-5) → tricarbonyl(η4-2,5-diphenylthiophene dioxide)iron (132080-68-3)

Guidance literature:

In benzene; byproducts: 2,5-diphenylthiophene; Irradiation (UV/VIS); under inert gas; to a solution of the 2,5-DPTDO was added Fe(CO)5; was irradiated for 6 h at room temperature; CH2Cl2 also may be used as solvent; filtration; evapn. to dryness; chromy. (toluene); elution with toluene, ethyl acetate; recrystn. from pentane/CH2Cl2; elem. anal.;

DOI:10.1016/0022-328X(90)80095-H

Reference yield: 45.0%

diiron nonacarbonyl (15321-51-4) + 2,5-bis(phenyl)-thiophene-1,1-dioxide (51092-02-5) → tricarbonyl(η4-2,5-diphenylthiophene dioxide)iron (132080-68-3)

Guidance literature:

In tetrahydrofuran; byproducts: Fe3(CO)12; under inert gas; a solution of 2,5-DPTDO and Fe2(CO)9 was stirred for 4 h under exclusion of light; filtration; evapn. to dryness; chromy. with toluene; elution with toluene and then with ethyl acetate; elem. anal.;

DOI:10.1016/0022-328X(90)80095-H

Reference yield: 40.0%

tricarbonyl(η4-2,5-diphenylthiophene dioxide)iron (132080-68-3) → Fe(CO)2(P(C6H5)3)(C4H2(C6H5)2SO2) (132080-91-2)

Guidance literature:

With PPh₃; In toluene; Irradiation (UV/VIS); under inert gas; PPh3 and the Fe-complex were irradiated for 6 h; filtration; dried in vacuo;;

DOI:10.1016/0022-328X(90)80095-H

upstream raw materials:

iron pentacarbonyl

2,5-bis(phenyl)-thiophene-1,1-dioxide

diiron nonacarbonyl

Downstream raw materials:

Fe(CO)2(P(C₆H₅)3)(C₄H₂(C₆H₅)2SO₂)