trans,trans,trans-[Ru(8-quinolinolato)2(4-chlorophenyl isocyanide)2]

Base Information

• Chemical Name: trans,trans,trans-[Ru(8-quinolinolato)2(4-chlorophenyl isocyanide)2]
• CAS No.: 1191080-70-2
• Molecular Formula: C₃₂H₂₀Cl₂N₄O₂Ru
• Molecular Weight: 664.512
• Mol file: 1191080-70-2.mol

Synonyms:

Chemical Property of trans,trans,trans-[Ru(8-quinolinolato)2(4-chlorophenyl isocyanide)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of trans,trans,trans-[Ru(8-quinolinolato)2(4-chlorophenyl isocyanide)2]

There total 1 articles about trans,trans,trans-[Ru(8-quinolinolato)2(4-chlorophenyl isocyanide)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

tris(8-quinolinolato-N(1),O(8))ruthenium(III) (97373-74-5,111321-91-6,82602-13-9) + p-chlorophenyl isocyanide (1885-81-0) → trans,trans,trans-[Ru(8-quinolinolato)2(4-chlorophenyl isocyanide)2] (1191080-70-2,1191251-44-1) + cis,cis,trans-[Ru(8-quinolinolato)2(4-chlorophenyl isocyanide)2]

Guidance literature:

With Zn#Hg; In ethanol; refluxed under Ar; cooled to room temp., filtered, evapd. (vac.), dissolved in CH2Cl2, chromd. (silica gel, CH2Cl2/acetone), dried (vac.), recrystd. (CH2Cl2/n-hexane); elem. anal.;

DOI:10.1021/om900253h

upstream raw materials:

tris(8-quinolinolato-N⁽¹⁾,O⁽⁸⁾)ruthenium(III)

p-chlorophenyl isocyanide

Refernces