[3,3'-bis(1,1'-dimethylethyl)-2,2'-diphenyl-1,1'-bi-1H-phosphirene-κP(1)]tetracarbonyliron

Base Information

• Chemical Name: [3,3'-bis(1,1'-dimethylethyl)-2,2'-diphenyl-1,1'-bi-1H-phosphirene-κP(1)]tetracarbonyliron
• CAS No.: 207223-47-0
• Molecular Formula: C₂₈H₂₈FeO₄P₂
• Molecular Weight: 546.322
• Mol file: 207223-47-0.mol

Synonyms:

Chemical Property of [3,3'-bis(1,1'-dimethylethyl)-2,2'-diphenyl-1,1'-bi-1H-phosphirene-κP(1)]tetracarbonyliron

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [3,3'-bis(1,1'-dimethylethyl)-2,2'-diphenyl-1,1'-bi-1H-phosphirene-κP(1)]tetracarbonyliron

There total 2 articles about [3,3'-bis(1,1'-dimethylethyl)-2,2'-diphenyl-1,1'-bi-1H-phosphirene-κP(1)]tetracarbonyliron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

disodium tetracarbonylferrate + 1-chloro-3-(1,1-dimethylethyl)-2-phenyl-1H-phosphirene (118398-71-3) → [3,3'-bis(1,1'-dimethylethyl)-2,2'-diphenyl-1,1'-bi-1H-phosphirene-κP(1)]tetracarbonyliron (207223-47-0)

Guidance literature:

In not given; byproducts: NaCl; elem. anal.;

DOI:10.1039/a709127c

Reference yield: 58.0%

disodium tetracarbonylferrate + 1-chloro-3-(1,1-dimethylethyl)-2-phenyl-1H-phosphirene (118398-71-3) → η(3:3)-(bis(Ph)(t-Bu)phosphirenylium)dicarbonyliron + [3,3'-bis(1,1'-dimethylethyl)-2,2'-diphenyl-1,1'-bi-1H-phosphirene-κP(1)]tetracarbonyliron (207223-47-0)

Guidance literature:

In diethyl ether; byproducts: NaCl; all manipulations under Ar atm., to suspn. of Fe complex added dropwise with stirring at -78° soln. of P compd.; allowed to warm to room temp., solvent evapd. in vac., chromy., solvent evapd. to dryness, recrystd. from n-pentane at -28°C, elem. anal., mixt. of two diastereomers;

DOI:10.1002/1099-0682(200108)2001:8<2067::AID-EJIC2067>3.0.CO;2-R

Reference yield: 63.0%

diiron nonacarbonyl (15321-51-4) + [3,3'-bis(1,1'-dimethylethyl)-2,2'-diphenyl-1,1'-bi-1H-phosphirene-κP(1)]tetracarbonyliron (207223-47-0) → μ-[3,3'-bis(1,1'-dimethylethyl)-2,2'-diphenyl-1,1'-bi-1H-phosphirene-κP(1):κP(1')]octacarbonyldiiron (207223-49-2)

Guidance literature:

In pentane; byproducts: Fe(CO)5; all manipulations under Ar atm.; mixt. of diastereomers of P compd. dissolved in pentane, treated with excess of Fe complex, stirred at room temp. for 24 h; solvent evapd. to dryness, chromy., recrystd. from n-pentane, elem. anal., mixt. of two diastereomers;

DOI:10.1002/1099-0682(200108)2001:8<2067::AID-EJIC2067>3.0.CO;2-R

upstream raw materials:

1-chloro-3-(1,1-dimethylethyl)-2-phenyl-1H-phosphirene

Downstream raw materials:

μ-[3,3'-bis(1,1'-dimethylethyl)-2,2'-diphenyl-1,1'-bi-1H-phosphirene-κP(1):κP(1')]octacarbonyldiiron