Fe(C₅H₄BBrNSi(CH₃)3BrC₆H₄)2

Base Information

• Chemical Name: Fe(C₅H₄BBrNSi(CH₃)3BrC₆H₄)2
• CAS No.: 507229-55-2
• Molecular Formula: C₂₈H₃₄B₂Br₄FeN₂Si₂
• Molecular Weight: 851.847
• Mol file: 507229-55-2.mol

Synonyms:

Chemical Property of Fe(C₅H₄BBrNSi(CH₃)3BrC₆H₄)2

Chemical Property:

Purity/Quality:

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Technology Process of Fe(C₅H₄BBrNSi(CH₃)3BrC₆H₄)2

There total 1 articles about Fe(C₅H₄BBrNSi(CH₃)3BrC₆H₄)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

1,1'-bis(dibromoboryl)ferrocene + 2-(4-bromophenyl)-1,1,1,3,3,3-hexamethyldisilazane (5089-33-8) → Fe(C5H4BBrNSi(CH3)3BrC6H4)2 (507229-55-2)

Guidance literature:

In toluene; Fe-complex in toluene was added dropwise with stirring at ambient temp. to ligand in toluene under Ar, stirred for 5 h at ambient temp.; vol. was reduced in vacuo, stored at -30°C for 12 h, filtered, triturated with C5H12, dried in vacuo;

DOI:10.1016/S0022-328X(02)01968-X

Reference yield: 91.0%

1,1'-bis(dibromoboryl)ferrocene + Fe(C5H4BBrNSi(CH3)3BrC6H4)2 (507229-55-2) → 1,3-dibora-[3]ferrocenophane (507229-59-6)

Guidance literature:

In toluene; Fe-complex in toluene was added with stirring to Fe-complex in toluene at -78°C, warmed to room temp., refluxed for 2.5 h, cooled to ambient temp. under Ar; slowly evapd. in vacuo;

DOI:10.1016/S0022-328X(02)01968-X

upstream raw materials:

2-(4-bromophenyl)-1,1,1,3,3,3-hexamethyldisilazane

Downstream raw materials:

1,3-dibora-[3]ferrocenophane