[Os(triphenylphosphine)2(CO)(OC₆H₃(CH₃)NNN₆H₃CH₃)]PF₆

Base Information

• Chemical Name: [Os(triphenylphosphine)2(CO)(OC₆H₃(CH₃)NNN₆H₃CH₃)]PF₆
• CAS No.: 602314-75-0
• Molecular Formula: C₅₁H₄₂N₂O₂OsP₂*F₆P
• Molecular Weight: 1112.02
• Mol file: 602314-75-0.mol

Synonyms:

Chemical Property of [Os(triphenylphosphine)2(CO)(OC₆H₃(CH₃)NNN₆H₃CH₃)]PF₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Os(triphenylphosphine)2(CO)(OC₆H₃(CH₃)NNN₆H₃CH₃)]PF₆

There total 1 articles about [Os(triphenylphosphine)2(CO)(OC₆H₃(CH₃)NNN₆H₃CH₃)]PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

ammonium hexafluorophosphate + Os(triphenylphosphine)2(CO)(OC6H3(CH3)NNC6H3CH3) (602314-67-0) → [Os(triphenylphosphine)2(CO)(OC6H3(CH3)NNN6H3CH3)]PF6 (602314-75-0)

Guidance literature:

In dichloromethane; acetonitrile; Electrolysis; coulometrical oxidn. of dichloromethane-acetonitrile (1:9) soln. of Os complex contg. NH4PF6 (0.1 M) at 0.9 V vs. SCE; evapn. to dryness under reduced pressure, washing the residue with ice-cold water, crying under vac. over P4O10;

DOI:10.1021/ic0343713

Reference yield:

[Os(triphenylphosphine)2(CO)(OC6H3(CH3)NNN6H3CH3)]PF6 (602314-75-0) → Os(triphenylphosphine)2(CO)(OC6H3(CH3)NNC6H3CH3) (602314-67-0)

Guidance literature:

With Os(II)(bpy)Br₂; TBAP; In acetonitrile; addn. of Os(II)(bpy)Br2 and TBAP to acetonitrile soln. of the Os(III) complex; not isolated, detected by cyclic voltammetry;

DOI:10.1021/ic0343713

upstream raw materials:

Os(triphenylphosphine)2(CO)(OC₆H₃(CH₃)NNC₆H₃CH₃)

Downstream raw materials:

Os(triphenylphosphine)2(CO)(OC₆H₃(CH₃)NNC₆H₃CH₃)