trans-RhCl(CO)(PEt₂Ph)2

Base Information

Chemical Name:trans-RhCl(CO)(PEt₂Ph)2
CAS No.:15691-93-7
Molecular Formula:C₂₁H₃₀ClOP₂Rh
Molecular Weight:498.775
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of trans-RhCl(CO)(PEt₂Ph)2

Chemical Property:

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Technology Process of trans-RhCl(CO)(PEt₂Ph)2

There total 6 articles about trans-RhCl(CO)(PEt₂Ph)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: di-μ-chloro-bis[bis(cyclo-octene)rhodium]

: 1605-53-4
diethyl-phenyl-phosphine

: 15691-93-7,29553-46-6
trans-RhCl(CO)(PEt₂Ph)2

Guidance literature:: With CO; In light petroleum; stirring Rh-complex with organic compound in light petroleum under argon for 20 h, removing solvent in vac., dissolving product in Et2O, bubbling CO through the soln. for 5 min; concg., holding at -30°C for 18 h, filtn., washing (cold Et2O) at -50°C, drying in vac.;
DOI:10.1039/DT9940001963

Reference yield:

: di(rhodium)tetracarbonyl dichloride

: 1605-53-4
diethyl-phenyl-phosphine

: 15691-93-7,29553-46-6
trans-RhCl(CO)(PEt₂Ph)2

Guidance literature:: In hexane; stoichiometric amount of phosphine;
DOI:10.1016/0022-328X(91)80251-E

Reference yield:

: RhCl(η(2)-O2)(PEt2Ph)3

: 124-38-9,18923-20-1
carbon dioxide

: 15137-12-9,16634-14-3,21839-98-5
mer-Rh(C6H5PEt2)3Cl3

: 15691-93-7,29553-46-6
trans-RhCl(CO)(PEt₂Ph)2

: 25504-23-8
RhCl(PEt₂Ph₃)3

: 360783-38-6
mer-RhCl(CO₃)(PEt₂Ph₃)3

Guidance literature:: In dichloromethane-d2; byproducts: O=PEt2Ph; absence of air and moisture; warming from 213 to 273 K, standing for fewmin; not isolated, reaction followed by NMR spectroscopy;