1-Naphthyl sulfone

Base Information

• Chemical Name: 1-Naphthyl sulfone
• CAS No.: 13250-03-8
• Molecular Formula: C20H14O2S
• Molecular Weight: 318.38900
• Hs Code.: 2904100000
• European Community (EC) Number: 685-952-0
• UNII: 6JTT904A64
• DSSTox Substance ID: DTXSID10357517
• Nikkaji Number: J173.403B
• Wikidata: Q82137464
• Mol file: 13250-03-8.mol

Synonyms:13250-03-8;1-NAPHTHYL SULFONE;Naphthalene, 1,1'-sulfonylbis-;1-naphthalen-1-ylsulfonylnaphthalene;Bis(1-naphthyl) sulfone;1,1'-Dinaphthyl sulfone;Bis(1-naphthalenyl) sulfone;1,1'-Sulfonylbis(naphthalene);6JTT904A64;Bis(1-naphtyl) sulfone;1,1'-Sulfonyldinaphthalene;UNII-6JTT904A64;1-(naphthalene-1-sulfonyl)naphthalene;SCHEMBL547461;DTXSID10357517;AKOS024339549

Chemical Property of 1-Naphthyl sulfone

Chemical Property:

• Melting Point: 187 °C
• Boiling Point: 557.6±19.0 °C(Predicted)
• PSA: 42.52000
• Density: 1.294±0.06 g/cm3(Predicted)
• LogP: 5.90660
• XLogP3: 5.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 318.07145086
• Heavy Atom Count: 23
• Complexity: 466

Purity/Quality:

99% ^*data from raw suppliers

1-NAPHTHYL SULFONE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C=CC=C2S(=O)(=O)C3=CC=CC4=CC=CC=C43

Technology Process of 1-Naphthyl sulfone

There total 6 articles about 1-Naphthyl sulfone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

bis(1-naphthyl)sulfide (607-53-4) → 1,1'-dinaphthyl sulfone (13250-03-8)

Guidance literature:

With sodium perborate monohydrate; acetic acid; at 50 ℃;

DOI:10.1055/s-0029-1217986

Reference yield: 73.0%

sodium naphthalene-1-sulfinate (64326-13-2) → 1,1'-dinaphthyl sulfone (13250-03-8)

Guidance literature:

With copper diacetate; In acetonitrile; at 60 ℃; for 3h;

DOI:10.3184/174751914X13946336636551

Reference yield: 17.0%

1,1'-sulfinyldinaphthalene (13285-00-2) → 1,1'-dinaphthyl sulfone (13250-03-8)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 ℃; for 0.25h;

DOI:10.1021/ja401383q

upstream raw materials:

bis(1-naphthyl)sulfide

1,1'-sulfinyldinaphthalene

bis(phenylsulfonyl)sulfide

naphthalene