(1R,3R)-1-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-1-(4-methoxy-benzyloxy)-hex-5-en-3-ol

Base Information

Chemical Name:(1R,3R)-1-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-1-(4-methoxy-benzyloxy)-hex-5-en-3-ol
CAS No.:150843-59-7
Molecular Formula:C₁₉H₂₈O₅
Molecular Weight:336.428
Hs Code.:

Synonyms:

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Chemical Property of (1R,3R)-1-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-1-(4-methoxy-benzyloxy)-hex-5-en-3-ol

Chemical Property:

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Technology Process of (1R,3R)-1-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-1-(4-methoxy-benzyloxy)-hex-5-en-3-ol

There total 1 articles about (1R,3R)-1-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-1-(4-methoxy-benzyloxy)-hex-5-en-3-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 2746-25-0
p-Methoxybenzyl bromide

: 150843-59-7
(1R,3R)-1-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-1-(4-methoxy-benzyloxy)-hex-5-en-3-ol

Guidance literature:: Multi-step reaction with 2 steps

2: diethyl ether / -78 °C

In diethyl ether;
DOI:10.1016/S0040-4039(00)79197-0

Reference yield:

: 150843-59-7
(1R,3R)-1-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-1-(4-methoxy-benzyloxy)-hex-5-en-3-ol

: 150843-62-2
(2S,6S,7R,8aS)-7-(4-Methoxy-benzyloxy)-octahydro-indolizine-2,6-diol

Guidance literature:: Multi-step reaction with 9 steps

1: imidazole / dimethylformamide

2: 1) hydroquinone 9-phenanthryl ether, K₃Fe(CN)6, K₂O₂O₄*2H₂O, 2) p-TsOH

3: Bu₄NF / tetrahydrofuran

4: NEt₃ / CH₂Cl₂

5: NaN₃ / dimethylformamide

6: Dowex-50 / methanol / 40 °C

7: pyridine / 0 °C

8: H₂ / Pd/CaCO₃ poisoned with Pb / ethanol

9: K₂CO₃ / ethanol / 50 °C

With pyridine; 1H-imidazole; potassium osmate(VI); sodium azide; Dowex-50; hydroquinone 9-phenanthryl ether; tetrabutyl ammonium fluoride; hydrogen; potassium carbonate; toluene-4-sulfonic acid; triethylamine; potassium hexacyanoferrate(III); Lindlar's catalyst; In tetrahydrofuran; methanol; ethanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(00)79197-0

Reference yield:

: 150843-59-7
(1R,3R)-1-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-1-(4-methoxy-benzyloxy)-hex-5-en-3-ol

: C₃₀H₃₉NO₁₀S₂

Guidance literature:: Multi-step reaction with 8 steps

1: imidazole / dimethylformamide

2: 1) hydroquinone 9-phenanthryl ether, K₃Fe(CN)6, K₂O₂O₄*2H₂O, 2) p-TsOH

3: Bu₄NF / tetrahydrofuran

4: NEt₃ / CH₂Cl₂

5: NaN₃ / dimethylformamide

6: Dowex-50 / methanol / 40 °C

7: pyridine / 0 °C

8: H₂ / Pd/CaCO₃ poisoned with Pb / ethanol

With pyridine; 1H-imidazole; potassium osmate(VI); sodium azide; Dowex-50; hydroquinone 9-phenanthryl ether; tetrabutyl ammonium fluoride; hydrogen; toluene-4-sulfonic acid; triethylamine; potassium hexacyanoferrate(III); Lindlar's catalyst; In tetrahydrofuran; methanol; ethanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(00)79197-0