[5,10,15-tris(2,6-dichlorophenyl)corrolato]cobalt(III)

Base Information

• Chemical Name: [5,10,15-tris(2,6-dichlorophenyl)corrolato]cobalt(III)
• CAS No.: 710949-74-9
• Molecular Formula: C₃₇H₁₇Cl₆CoN₄
• Molecular Weight: 789.28
• Mol file: 710949-74-9.mol

Synonyms:

Chemical Property of [5,10,15-tris(2,6-dichlorophenyl)corrolato]cobalt(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [5,10,15-tris(2,6-dichlorophenyl)corrolato]cobalt(III)

There total 2 articles about [5,10,15-tris(2,6-dichlorophenyl)corrolato]cobalt(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

5,10,15-tris(2,6-dichlorophenyl)corrole + cobalt(II) diacetate tetrahydrate (6147-53-1) → [5,10,15-tris(2,6-dichlorophenyl)corrolato]cobalt(III) (710949-74-9)

Guidance literature:

In methanol; chloroform; stirring and refluxing corrole and Co salt in CHCl3-CH3OH mixt. (7:3 vol.) for 90 min; evapn., dissolving in CH2Cl2, washing with water, drying over MgSO4, evapn., chromy. (basic alumina, CH2Cl2), recrystn. from CH2Cl2-methanol; elem. anal.;

DOI:10.1039/b316706b

Reference yield:

5,10,15-tris(2,6-dichlorophenyl)corrole + cobalt(II) diacetate tetrahydrate (6147-53-1) → [5,10,15-tris(2,6-dichlorophenyl)corrolato]cobalt(III) (710949-74-9)

Guidance literature:

In methanol; chloroform; for 1.5h; Catalytic behavior; Reflux;

DOI:10.1002/cctc.201700349

upstream raw materials:

cobalt(II) diacetate tetrahydrate