(1,2-bis(diethylphosphino)ethane)Ni(Me)(pentafluorothiophenolate)

Base Information

Chemical Name:(1,2-bis(diethylphosphino)ethane)Ni(Me)(pentafluorothiophenolate)
CAS No.:1174330-30-3
Molecular Formula:C₁₇H₂₇F₅NiP₂S
Molecular Weight:479.097
Hs Code.:

Synonyms:

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Chemical Property of (1,2-bis(diethylphosphino)ethane)Ni(Me)(pentafluorothiophenolate)

Chemical Property:

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Technology Process of (1,2-bis(diethylphosphino)ethane)Ni(Me)(pentafluorothiophenolate)

There total 8 articles about (1,2-bis(diethylphosphino)ethane)Ni(Me)(pentafluorothiophenolate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: (1,2-bis(diethylphosphino)ethane)Ni⁽⁰⁾Me₂

: 771-62-0
pentafluorophenylthiol

: 1174330-30-3
(1,2-bis(diethylphosphino)ethane)Ni(Me)(pentafluorothiophenolate)

Guidance literature:: In diethyl ether; byproducts: CH4; (N2, Schlenk techniques); dropwise addn. of soln of C6F5SH in ethyl ether to soln. of nickel compd. in ethyl ether at -78°C, stirring for2 h with gradually increasing temp. to ambient temp.; addn. of pentane, isolation of solid, washing with pentane, drying undervacuum overnight, elem. anal.;
DOI:10.1039/b901192g

Reference yield:

: 6411-21-8
depe

: 1174330-30-3
(1,2-bis(diethylphosphino)ethane)Ni(Me)(pentafluorothiophenolate)

Guidance literature:: Multi-step reaction with 2 steps

1: diethyl ether

2: diethyl ether

In diethyl ether;
DOI:10.1039/b901192g

Reference yield:

: 1174330-29-0
(1,2-bis(diethylphosphino)ethane)Ni(Me)(thiophenolate)

: 1174330-25-6
(1,2-bis(diphenylphosphino)ethane)Ni(Me)(pentafluorothiophenolate)

: 115981-41-4
methyl(benzenethiolato){1,2-bis(diphenylphosphino)ethane}nickel

: 1174330-30-3
(1,2-bis(diethylphosphino)ethane)Ni(Me)(pentafluorothiophenolate)

Guidance literature:: In benzene-d6; (N2, Schlenk techniques); dissolving of nickel complexes separately in C6D6, mixing of nickel compd., ambient temp.; not isolated, detected by NMR;
DOI:10.1039/b901192g