[(MeTP)VCl(THF)]*THF

Base Information

• Chemical Name: [(MeTP)VCl(THF)]*THF
• CAS No.: 956511-07-2
• Molecular Formula: C₄H₈O*C₄₃H₃₉ClN₃OV
• Molecular Weight: 772.304
• Mol file: 956511-07-2.mol

Synonyms:

Chemical Property of [(MeTP)VCl(THF)]*THF

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of [(MeTP)VCl(THF)]*THF

There total 1 articles about [(MeTP)VCl(THF)]*THF which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.3%

Vanadium (III) chloride-(tris-tetrahydrofuran) (131063-11-1,16997-51-6,19559-06-9) + 2,5-((C4H3NH)C(C6H5)2)2C4H2N(Me) (869115-51-5) → [(MeTP)VCl(THF)]*THF (956511-07-2)

Guidance literature:

With KH; In tetrahydrofuran; under N2; soln. of ligand in THF treated with KH, mixt. stirred for 4 h,V compd. added, stirred overnight; centrifugation, soln. layered with hexanes, crystd. after several d; elem. anal.;

DOI:10.1021/ic701219h

Reference yield: 39.4%

[(MeTP)VCl(THF)]*THF (956511-07-2) + toluene (108-88-3,15644-74-3,16713-13-6) → [(MeTP)V(THF)]*(toluene)0.5

Guidance literature:

With Na; In tetrahydrofuran; under N2; soln. of V complex in THF stirred with Na for ca. 4 h; evapd. under vac., residue dissolved in THF, centrifugation, toluene added to soln., crystd. at -35°C; elem. anal.;

DOI:10.1021/ic701219h

upstream raw materials:

Vanadium (III) chloride-(tris-tetrahydrofuran)

2,5-((C₄H₃NH)C(C₆H₅)2)2C₄H₂N(Me)