2,6,11,14-tetraazaheneicosanoic acid, 21-azido-13-<1-(2-naphthalenyl)ethoxy>-12,15-dioxo-6<(phenylmethoxy)carbonyl>-, phenylmethyl ester,

Base Information

Chemical Name:2,6,11,14-tetraazaheneicosanoic acid, 21-azido-13-<1-(2-naphthalenyl)ethoxy>-12,15-dioxo-6<(phenylmethoxy)carbonyl>-, phenylmethyl ester,
CAS No.:219740-92-8
Molecular Formula:C₄₄H₅₅N₇O₇
Molecular Weight:793.963
Hs Code.:

2,6,11,14-tetraazaheneicosanoic acid, 21-azido-13-<1-(2-naphthalenyl)ethoxy>-12,15-dioxo-6<(phenylmethoxy)carbonyl>-, phenylmethyl ester, <S-(R*,R*)>

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Chemical Property of 2,6,11,14-tetraazaheneicosanoic acid, 21-azido-13-<1-(2-naphthalenyl)ethoxy>-12,15-dioxo-6<(phenylmethoxy)carbonyl>-, phenylmethyl ester,

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Technology Process of 2,6,11,14-tetraazaheneicosanoic acid, 21-azido-13-<1-(2-naphthalenyl)ethoxy>-12,15-dioxo-6<(phenylmethoxy)carbonyl>-, phenylmethyl ester,

There total 2 articles about 2,6,11,14-tetraazaheneicosanoic acid, 21-azido-13-<1-(2-naphthalenyl)ethoxy>-12,15-dioxo-6<(phenylmethoxy)carbonyl>-, phenylmethyl ester, which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (7-Azido-heptanoylamino)-((S)-1-naphthalen-2-yl-ethoxy)-acetic acid methyl ester

: 219740-92-8
2,6,11,14-tetraazaheneicosanoic acid, 21-azido-13-<1-(2-naphthalenyl)ethoxy>-12,15-dioxo-6<(phenylmethoxy)carbonyl>-, phenylmethyl ester,

Guidance literature:: Multi-step reaction with 2 steps

1: 98 percent / aq. NaOH / 1,2-dimethoxy-ethane / 1.5 h / Ambient temperature

2: 1.) hydroxybenzotriazole, DCC / 1) CH₂Cl₂, rt, 30 min; 2) CH₂Cl₂, rt, 48 h

With sodium hydroxide; benzotriazol-1-ol; dicyclohexyl-carbodiimide; In 1,2-dimethoxyethane;
DOI:10.1021/jo9811118

Reference yield:

: 97628-87-0
benzyl (4-aminobutyl)(3-(((benzyloxy)carbonyl)amino)propyl)carbamate

: (7-Azido-heptanoylamino)-((S)-1-naphthalen-2-yl-ethoxy)-acetic acid

: 219740-92-8
2,6,11,14-tetraazaheneicosanoic acid, 21-azido-13-<1-(2-naphthalenyl)ethoxy>-12,15-dioxo-6<(phenylmethoxy)carbonyl>-, phenylmethyl ester,

: 2,6,11,14-tetraazaheneicosanoic acid, 21-azido-13-<1-(2-naphthalenyl)ethoxy>-12,15-dioxo-6<(phenylmethoxy)carbonyl>-, phenylmethyl ester,

Guidance literature:: With benzotriazol-1-ol; dicyclohexyl-carbodiimide; Yield given; Multistep reaction; 1) CH₂Cl₂, rt, 30 min; 2) CH₂Cl₂, rt, 48 h;
DOI:10.1021/jo9811118

Reference yield:

: 219740-92-8
2,6,11,14-tetraazaheneicosanoic acid, 21-azido-13-<1-(2-naphthalenyl)ethoxy>-12,15-dioxo-6<(phenylmethoxy)carbonyl>-, phenylmethyl ester,

: 85468-01-5
(S)-(-)-15-deoxyspergualin tri-hydrochloride

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) Ph₃P / 1) water, THF, reflux, overnight; 2) water, THF, rt, 3 h

2: 1.) aq. AcOH, H₂, 2.) Sephadex C-25, Sephadex LH-20 / 1.) Pearlman's catalyst / 1) methanol, 1 atm, rt, 8 h

With Sephadex C-25; Sephadex LH-20; hydrogen; acetic acid; triphenylphosphine; palladium dihydroxide;
DOI:10.1021/jo9811118