but-2-enoato(diphenylphosphino but-2-enoate)(triphenylphosphine)rhodium(I)

Base Information

• Chemical Name: but-2-enoato(diphenylphosphino but-2-enoate)(triphenylphosphine)rhodium(I)
• CAS No.: 136776-57-3
• Molecular Formula: C₃₈H₃₅O₄P₂Rh
• Molecular Weight: 720.547
• Mol file: 136776-57-3.mol

Synonyms:

Chemical Property of but-2-enoato(diphenylphosphino but-2-enoate)(triphenylphosphine)rhodium(I)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of but-2-enoato(diphenylphosphino but-2-enoate)(triphenylphosphine)rhodium(I)

There total 7 articles about but-2-enoato(diphenylphosphino but-2-enoate)(triphenylphosphine)rhodium(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

(diphenylphosphino butyrate)bis(triphenylphosphine)rhodium(I) hexafluorophosphate (136842-01-8) + potassium crotanoate (59471-15-7) → but-2-enoato(diphenylphosphino but-2-enoate)(triphenylphosphine)rhodium(I) (136776-57-3)

Guidance literature:

In dichloromethane; stirred for 10 h, filtered the excess of K(O2CCHCHMe, evapd. in vac., light petroleum added, filtered off and dried in vac.;

DOI:10.1039/DT9910001929

Reference yield: 80.0%

(diphenylphosphino butyrate)bis(triphenylphosphine)rhodium(I) hexafluorophosphate (136842-01-8) + {NH(C2H5)3}(1+)*{(CH3)CHCHCO2}(1-)={NH(C2H5)3}{(CH3)CHCHCO2} (50807-07-3) → but-2-enoato(diphenylphosphino but-2-enoate)(triphenylphosphine)rhodium(I) (136776-57-3)

Guidance literature:

10 times excess of triethylammonium salt of (MeCHCHCO2)(1-);

DOI:10.1039/DT9910001929

Reference yield: 73.0%

{RhCl((C6H5)3P)((C6H5)2PO2CCHCHCH3)} (128025-04-7) + potassium crotanoate (59471-15-7) → but-2-enoato(diphenylphosphino but-2-enoate)(triphenylphosphine)rhodium(I) (136776-57-3)

Guidance literature:

In tetrahydrofuran; stirred for 2 h, filtered to eliminate the excess of K(O2CCHCHMe), evapd. under vac., light petroleum added, filtered off and dried under vac.; elem. anal.;

DOI:10.1039/DT9910001929

upstream raw materials:

2-butenoic acid

{RhCl(P(C₆H₅)3)2((C₆H₅)2PO₂CC(CH₃)CH(C₆H₅))}

{RhCl((C₆H₅)3P)((C₆H₅)2PO₂CCHCHCH₃)}

potassium crotanoate