η5-pentamethylcyclopentadienyl[N-(2-methylquinolin-8-yl)-p-methylbenzamide]titanium dichloride

Base Information

• Chemical Name: η5-pentamethylcyclopentadienyl[N-(2-methylquinolin-8-yl)-p-methylbenzamide]titanium dichloride
• CAS No.: 1227096-19-6
• Molecular Formula: C₂₈H₃₀Cl₂N₂OTi
• Molecular Weight: 529.345
• Mol file: 1227096-19-6.mol

Synonyms:

Chemical Property of η5-pentamethylcyclopentadienyl[N-(2-methylquinolin-8-yl)-p-methylbenzamide]titanium dichloride

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of η5-pentamethylcyclopentadienyl[N-(2-methylquinolin-8-yl)-p-methylbenzamide]titanium dichloride

There total 1 articles about η5-pentamethylcyclopentadienyl[N-(2-methylquinolin-8-yl)-p-methylbenzamide]titanium dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.2%

Cp*TiCl3 (12129-06-5) + 4-methyl-N-(2-methylquinolin-8-yl)benzamide (901350-67-2) → η5-pentamethylcyclopentadienyl[N-(2-methylquinolin-8-yl)-p-methylbenzamide]titanium dichloride (1227096-19-6)

Guidance literature:

With KH; In tetrahydrofuran; KH added to stirred soln. of ligand in dried THF at room temp.; stirred for 12 h; soln. of Ti complex in THF added dropwise at -78°C over30 min; warmed to room temp.; stirred for 12 h; solvent removed under vac.; extd. with toluene; combined filtrates concd. under vac.; filtered; elem. anal.;

DOI:10.1021/om1000748

upstream raw materials:

Cp*TiCl₃

4-methyl-N-(2-methylquinolin-8-yl)benzamide