Technology Process of C29H36O5Si
There total 3 articles about C29H36O5Si which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
trimethylsulphonium iodide;
With
n-butyllithium;
In
tetrahydrofuran;
at -40 - -15 ℃;
for 1.5h;
C28H32O4Si;
In
tetrahydrofuran;
at -40 - 20 ℃;
With
water; sodium acetate;
In
N,N-dimethyl-formamide;
at 90 ℃;
for 2h;
DOI:10.1021/ja305322x
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: 1H-imidazole / N,N-dimethyl-formamide / 12 h / 20 °C
2.1: sodium hydride; tetra-(n-butyl)ammonium iodide / N,N-dimethyl-formamide; mineral oil / 12 h / 0 - 20 °C
3.1: triethylsilane; boron trifluoride diethyl etherate / dichloromethane / 4 h / 0 - 20 °C
4.1: acetic anhydride; dipyridinium dichromate / dichloromethane / 12 h / 20 °C
5.1: n-butyllithium / tetrahydrofuran / 1.5 h / -40 - -15 °C
5.2: -40 - 20 °C
5.3: 2 h / 90 °C
With
1H-imidazole; triethylsilane; dipyridinium dichromate; n-butyllithium; boron trifluoride diethyl etherate; acetic anhydride; tetra-(n-butyl)ammonium iodide; sodium hydride;
In
tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; mineral oil;
DOI:10.1021/ja305322x
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: acetic anhydride; dipyridinium dichromate / dichloromethane / 12 h / 20 °C
2.1: n-butyllithium / tetrahydrofuran / 1.5 h / -40 - -15 °C
2.2: -40 - 20 °C
2.3: 2 h / 90 °C
With
dipyridinium dichromate; n-butyllithium; acetic anhydride;
In
tetrahydrofuran; dichloromethane;
DOI:10.1021/ja305322x
