ortho-dimethyltetrathiafulvalene-2′-(N-benzyl-1,2,3-triazol-5-yl)-3′-ethynyl

Base Information

Chemical Name:ortho-dimethyltetrathiafulvalene-2′-(N-benzyl-1,2,3-triazol-5-yl)-3′-ethynyl
CAS No.:1608150-92-0
Molecular Formula:C₁₉H₁₅N₃S₄
Molecular Weight:413.612
Hs Code.:

Synonyms:

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Chemical Property of ortho-dimethyltetrathiafulvalene-2′-(N-benzyl-1,2,3-triazol-5-yl)-3′-ethynyl

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Technology Process of ortho-dimethyltetrathiafulvalene-2′-(N-benzyl-1,2,3-triazol-5-yl)-3′-ethynyl

There total 3 articles about ortho-dimethyltetrathiafulvalene-2′-(N-benzyl-1,2,3-triazol-5-yl)-3′-ethynyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1608150-91-9
2,3-di(trimethylsilylethynyl)-6,7-dimethyltetrathiafulvalene

: 1608150-92-0
ortho-dimethyltetrathiafulvalene-2′-(N-benzyl-1,2,3-triazol-5-yl)-3′-ethynyl

Guidance literature:: Multi-step reaction with 2 steps

1: tetrabutyl ammonium fluoride / tetrahydrofuran; methanol / 0.75 h / 20 °C

2: copper(l) iodide; N-ethyl-N,N-diisopropylamine / chloroform / 65 °C / Schlenk technique

With copper(l) iodide; tetrabutyl ammonium fluoride; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; methanol; chloroform;
DOI:10.1039/c4ob00148f

Reference yield:

: 62024-60-6
3,4-dimethyltetrathiafulvalene

: 1608150-92-0
ortho-dimethyltetrathiafulvalene-2′-(N-benzyl-1,2,3-triazol-5-yl)-3′-ethynyl

Guidance literature:: Multi-step reaction with 4 steps

1.1: N-ethyl-N,N-diisopropylamine; n-butyllithium / hexane; diethyl ether / 1 h / -78 °C / Schlenk technique; Inert atmosphere

1.2: 20 °C / Schlenk technique; Inert atmosphere

2.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; copper(l) iodide; N-ethyl-N,N-diisopropylamine / tetrahydrofuran / Schlenk technique; Inert atmosphere; Heating

3.1: tetrabutyl ammonium fluoride / tetrahydrofuran; methanol / 0.75 h / 20 °C

4.1: copper(l) iodide; N-ethyl-N,N-diisopropylamine / chloroform / 65 °C / Schlenk technique

With copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; tetrabutyl ammonium fluoride; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; methanol; diethyl ether; hexane; chloroform; 2.1: |Sonogashira Cross-Coupling;
DOI:10.1039/c4ob00148f

Reference yield:

: 172880-08-9
2,3-diiodo-6,7-dimethyltetrathiafulvalene

: 1608150-92-0
ortho-dimethyltetrathiafulvalene-2′-(N-benzyl-1,2,3-triazol-5-yl)-3′-ethynyl

Guidance literature:: Multi-step reaction with 3 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; copper(l) iodide; N-ethyl-N,N-diisopropylamine / tetrahydrofuran / Schlenk technique; Inert atmosphere; Heating

2: tetrabutyl ammonium fluoride / tetrahydrofuran; methanol / 0.75 h / 20 °C

3: copper(l) iodide; N-ethyl-N,N-diisopropylamine / chloroform / 65 °C / Schlenk technique

With copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; tetrabutyl ammonium fluoride; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; methanol; chloroform; 1: |Sonogashira Cross-Coupling;
DOI:10.1039/c4ob00148f