3H-Indolium, 1,2,3,3-tetramethyl-, perchlorate

Base Information

• Chemical Name: 3H-Indolium, 1,2,3,3-tetramethyl-, perchlorate
• CAS No.: 13330-41-1
• Molecular Formula: C12H16N.ClO4
• Molecular Weight: 273.716
• DSSTox Substance ID: DTXSID90464839
• Mol file: 13330-41-1.mol

Synonyms:13330-41-1;3H-Indolium, 1,2,3,3-tetramethyl-, perchlorate (1:1);1,2,3,3-TETRAMETHYL-3H-INDOLIUM PERCHLORATE;3H-Indolium, 1,2,3,3-tetramethyl-, perchlorate;DTXSID90464839;AKOS002390498

Chemical Property of 3H-Indolium, 1,2,3,3-tetramethyl-, perchlorate

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 273.0767857
• Heavy Atom Count: 18
• Complexity: 346

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=[N+](C2=CC=CC=C2C1(C)C)C.[O-]Cl(=O)(=O)=O

Technology Process of 3H-Indolium, 1,2,3,3-tetramethyl-, perchlorate

There total 1 articles about 3H-Indolium, 1,2,3,3-tetramethyl-, perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,3,3-trimethyl-6'-[(E)-2-(1'',3'',3''-trimethylindolium-2''-yl)vinyl]-8'-benzyl-spiro[indolino-2,2'-2H-chromene] perchlorate → 1,3,3-trimethyl-6'-formyl-8'-benzyl-spiro[indolino-2,2'-2H-chromene] + 1,2,3,3-tetramethyl-3H-indolium perchlorate (13330-41-1)

Guidance literature:

With water; In acetonitrile;

DOI:10.1134/S0012500818100026

Reference yield: 94.0%

3-anilino-3-ferrocenylacrolein anyl hydrochloride + 1,2,3,3-tetramethyl-3H-indolium perchlorate (13330-41-1) → 2-(4-anilino-4-ferrocenyl-1,3-butadienyl)-1,3,3-trimethylindolinium perchlorate (92952-21-1)

Guidance literature:

With triethylamine; In ethanol; boiling a mixt. of Fe-complex, 1,2,3,3-tetramethylindolinium perchlorate, and two drops of triethylamine for 2 h; mixt. allowed to stand for 24 h at room temp.; crystals are filtered off, washed (ether); elem. anal.;

Reference yield: 90.0%

1,2,3,3-tetramethyl-3H-indolium perchlorate (13330-41-1) + 7-[(Z)-3-Ethoxy-prop-2-en-(Z)-ylidene]-2,4-diphenyl-6,7-dihydro-5H-cyclopenta[b]pyranylium; perchlorate → 1,3,3-Trimethyl-2-<4-(2,4-diphenyl-5,6-dihydrocyclopentapyran-7-yl)-1,3-butadienyl>-3H-indolium Perchlorate

Guidance literature:

With pyridine; In acetic anhydride; for 0.0833333h; Heating;

DOI:10.1007/BF00503524

Downstream raw materials:

(1,3,3-trimethyl-indolin-2-yliden)-acetaldehyde phenylimine; perchlorate

1-<(1,3,3-trimethylindolidene-2)ethylidene>-1-phenyl-3-isopropylpyrazolin-2-ylidene-4-thione-5