(5S,10S,11S,Z)-11-(benzyloxymethyl)-2,2,3,3,10,14,14-heptamethyl-13,13-diphenyl-5-((S)-1-((4R,5R)-2,2,5-trimethyl-1,3-dioxan-4-yl)ethyl)-4,12-dioxa-3,13 disilapentadec-7-ene

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Chemical Name:(5S,10S,11S,Z)-11-(benzyloxymethyl)-2,2,3,3,10,14,14-heptamethyl-13,13-diphenyl-5-((S)-1-((4R,5R)-2,2,5-trimethyl-1,3-dioxan-4-yl)ethyl)-4,12-dioxa-3,13 disilapentadec-7-ene
CAS No.:1252009-08-7
Molecular Formula:C₄₇H₇₂O₅Si₂
Molecular Weight:773.257
Hs Code.:

(5S,10S,11S,Z)-11-(benzyloxymethyl)-2,2,3,3,10,14,14-heptamethyl-13,13-diphenyl-5-((S)-1-((4R,5R)-2,2,5-trimethyl-1,3-dioxan-4-yl)ethyl)-4,12-dioxa-3,13 disilapentadec-7-ene

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Chemical Property of (5S,10S,11S,Z)-11-(benzyloxymethyl)-2,2,3,3,10,14,14-heptamethyl-13,13-diphenyl-5-((S)-1-((4R,5R)-2,2,5-trimethyl-1,3-dioxan-4-yl)ethyl)-4,12-dioxa-3,13 disilapentadec-7-ene

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Technology Process of (5S,10S,11S,Z)-11-(benzyloxymethyl)-2,2,3,3,10,14,14-heptamethyl-13,13-diphenyl-5-((S)-1-((4R,5R)-2,2,5-trimethyl-1,3-dioxan-4-yl)ethyl)-4,12-dioxa-3,13 disilapentadec-7-ene

There total 1 articles about (5S,10S,11S,Z)-11-(benzyloxymethyl)-2,2,3,3,10,14,14-heptamethyl-13,13-diphenyl-5-((S)-1-((4R,5R)-2,2,5-trimethyl-1,3-dioxan-4-yl)ethyl)-4,12-dioxa-3,13 disilapentadec-7-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1252009-11-2
(3S,4S)-3-(tert-butyldimethylsilyloxy)-4-((4R,5R)-2,2,5-trimethyl-1,3-dioxan-4-yl)pentanal

: 1252009-10-1
C₄₇H₅₂O₂PSi⁽¹⁺⁾*I^(1-)

: 1252009-08-7
(5S,10S,11S,Z)-11-(benzyloxymethyl)-2,2,3,3,10,14,14-heptamethyl-13,13-diphenyl-5-((S)-1-((4R,5R)-2,2,5-trimethyl-1,3-dioxan-4-yl)ethyl)-4,12-dioxa-3,13 disilapentadec-7-ene

: (5S,10S,11S,E)-11-(benzyloxymethyl)-2,2,3,3,10,14,14-heptamethyl-13,13-diphenyl-5-((S)-1-((4R,5R)-2,2,5-trimethyl-1,3-dioxan-4-yl)ethyl)-4,12-dioxa-3,13 disilapentadec-7-ene

Guidance literature:: C₄₇H₅₂O₂PSi⁽¹⁺⁾*I^(1-); With n-butyllithium; In tetrahydrofuran; hexane; at 23 ℃; for 1h;

(3S,4S)-3-(tert-butyldimethylsilyloxy)-4-((4R,5R)-2,2,5-trimethyl-1,3-dioxan-4-yl)pentanal; In tetrahydrofuran; hexane; at -78 - 23 ℃; optical yield given as %de;
DOI:10.1016/j.tetasy.2010.04.068