Technology Process of Benzene, 1,1'-(1,2-ethenediyl)bis[4-methoxy-3-(phenylmethoxy)-, (E)-
There total 1 articles about Benzene, 1,1'-(1,2-ethenediyl)bis[4-methoxy-3-(phenylmethoxy)-, (E)- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid;
In
dichloromethane; water;
Ambient temperature;
DOI:10.1016/S0040-4039(00)97306-4
- Guidance literature:
-
Multi-step reaction with 8 steps
1: OsCl3, dihydroquinidine 4-chlorobenzoate, N-methylmorpholine N-oxide / acetone; H2O / 24 h / Ambient temperature
2: SOCl2, Et3N / diethyl ether / 1 h / 0 deg C to r.t.
3: RuCl3, NaOCl / acetonitrile
4: 2 h / r.t. to 130 deg C
5: 85 percent / NaOAc / xylene / 2 h / Heating
6: 87 percent / aq. HCl / acetone / 0 deg C to r.t.
7: 85 percent / NaOAc / xylene / 2 h / Heating
8: 88 percent / H2 / 10percent Pd/C / propan-2-ol; H2O / 38000 Torr
With
hydrogenchloride; ruthenium trichloride; sodium hypochlorite; thionyl chloride; dihydroquinidine 4-chlorobenzoate; osmium (III) chloride; hydrogen; sodium acetate; 4-methylmorpholine N-oxide; triethylamine;
palladium on activated charcoal;
In
diethyl ether; water; isopropyl alcohol; acetone; acetonitrile; xylene;
DOI:10.1016/S0040-4039(00)97306-4