5-(3'',5''-dibromo-5'-phenyl-[1,1':2',1''-terphenyl]-3-yl)-4,6,7-triphenyltriphenyleno[1,12-abc]phenazine

Base Information

Chemical Name:5-(3'',5''-dibromo-5'-phenyl-[1,1':2',1''-terphenyl]-3-yl)-4,6,7-triphenyltriphenyleno[1,12-abc]phenazine
CAS No.:1409939-40-7
Molecular Formula:C₆₈H₄₀Br₂N₂
Molecular Weight:1044.89
Hs Code.:

Synonyms:

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Chemical Property of 5-(3'',5''-dibromo-5'-phenyl-[1,1':2',1''-terphenyl]-3-yl)-4,6,7-triphenyltriphenyleno[1,12-abc]phenazine

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Technology Process of 5-(3'',5''-dibromo-5'-phenyl-[1,1':2',1''-terphenyl]-3-yl)-4,6,7-triphenyltriphenyleno[1,12-abc]phenazine

There total 5 articles about 5-(3'',5''-dibromo-5'-phenyl-[1,1':2',1''-terphenyl]-3-yl)-4,6,7-triphenyltriphenyleno[1,12-abc]phenazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 1409939-39-4
10-(3'',5''-dibromo-5'-phenyl-[1,1':2',1''-terphenyl]-3-yl)-9,11,12-triphenylbenzo[e]pyrene-4,5-dione

: 95-54-5
1,2-diamino-benzene

: 1409939-40-7
5-(3'',5''-dibromo-5'-phenyl-[1,1':2',1''-terphenyl]-3-yl)-4,6,7-triphenyltriphenyleno[1,12-abc]phenazine

Guidance literature:: In ethanol; chloroform; at 65 ℃; for 12h; Inert atmosphere;
DOI:10.1021/ja309270h

Reference yield:

: 1225389-46-7
2-bromo-5-iodo-3'-(phenylethynyl)-1,1'-biphenyl

: 1409939-40-7
5-(3'',5''-dibromo-5'-phenyl-[1,1':2',1''-terphenyl]-3-yl)-4,6,7-triphenyltriphenyleno[1,12-abc]phenazine

Guidance literature:: Multi-step reaction with 6 steps

1.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / ethanol; toluene / 80 °C / Inert atmosphere

2.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C / Inert atmosphere; Cooling with acetone-dry ice

2.2: -78 - 20 °C / Inert atmosphere

3.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / ethanol; toluene / 85 °C / Inert atmosphere

4.1: diphenylether / 5 h / 240 °C / Inert atmosphere

5.1: sodium periodate; rhodium(III) chloride hydrate / dichloromethane; water; acetonitrile / 26 h / 20 °C / Inert atmosphere

6.1: ethanol; chloroform / 12 h / 65 °C / Inert atmosphere

With sodium periodate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; diphenylether; rhodium(III) chloride hydrate; potassium carbonate; In tetrahydrofuran; ethanol; hexane; dichloromethane; chloroform; water; toluene; acetonitrile;
DOI:10.1021/ja309270h

Reference yield:

: C₃₂H₂₉BO₂

: 1409939-40-7
5-(3'',5''-dibromo-5'-phenyl-[1,1':2',1''-terphenyl]-3-yl)-4,6,7-triphenyltriphenyleno[1,12-abc]phenazine

Guidance literature:: Multi-step reaction with 4 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / ethanol; toluene / 85 °C / Inert atmosphere

2: diphenylether / 5 h / 240 °C / Inert atmosphere

3: sodium periodate; rhodium(III) chloride hydrate / dichloromethane; water; acetonitrile / 26 h / 20 °C / Inert atmosphere

4: ethanol; chloroform / 12 h / 65 °C / Inert atmosphere

With sodium periodate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; diphenylether; rhodium(III) chloride hydrate; potassium carbonate; In ethanol; dichloromethane; chloroform; water; toluene; acetonitrile;
DOI:10.1021/ja309270h