[(η5-C5H4-CH2CH2PPh2-κP)Ru(MeCN)Cl]

Base Information

Chemical Name:[(η5-C5H4-CH2CH2PPh2-κP)Ru(MeCN)Cl]
CAS No.:647828-27-1
Molecular Formula:C₂₁H₂₁ClNPRu
Molecular Weight:454.901
Hs Code.:

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Chemical Property of [(η5-C5H4-CH2CH2PPh2-κP)Ru(MeCN)Cl]

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Technology Process of [(η5-C5H4-CH2CH2PPh2-κP)Ru(MeCN)Cl]

There total 1 articles about [(η5-C5H4-CH2CH2PPh2-κP)Ru(MeCN)Cl] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: dichloro-bis-μ-chloro-bis[(1-3η:6-8η)-2,7-dimethyloctadienediyl]diruthenium(II)

: 122470-20-6
(2-diphenylphosphinoethyl)cyclopentadiene

: 75-05-8,26809-02-9
acetonitrile

: 647828-27-1
[(η5-C5H4-CH2CH2PPh2-κP)Ru(MeCN)Cl]

Guidance literature:: With Li₂CO₃; In ethanol; acetonitrile; Ru-complex, Li2CO3 in mixt. of EtOH-MeCN were charged with flask, ligandin MeCN was added, stirred at room temp. for 16 h under N2; filtered, evapd. to dryness, dissolved in MeCN, filtered through alumina, solvent was evapd.;
DOI:10.1016/S0020-1693(02)01502-5

Reference yield: 81.0%

: 647828-27-1
[(η5-C5H4-CH2CH2PPh2-κP)Ru(MeCN)Cl]

: 603-35-0
triphenylphosphine

: 75-05-8,26809-02-9
acetonitrile

: [(η5-C5H4-CH2CH2PPh2-κP)Ru(PPh3)Cl]*MeCN

Guidance literature:: In acetonitrile; Ru-complex was dissolved in MeCN, PPh3 was added, stirred for 3 h under N2; concd., Et2O was added dropwise; elem. anal.;
DOI:10.1016/S0020-1693(02)01502-5