All-trans-beta-apo-8'-carotenal

Base Information

• Chemical Name: All-trans-beta-apo-8'-carotenal
• CAS No.: 4172-46-7
• Molecular Formula: C₃₀H₄₀O
• Molecular Weight: 416.647
• Mol file: 4172-46-7.mol

Synonyms:

Chemical Property of All-trans-beta-apo-8'-carotenal

Chemical Property:

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of All-trans-beta-apo-8'-carotenal

There total 39 articles about All-trans-beta-apo-8'-carotenal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

crocetindial (502-70-5) + C28H32ClP → trans-β-apo-8'-carotenal (1107-26-2,4172-46-7)

Guidance literature:

C₂₈H₃₂ClP; With sodium methylate; In methanol; at 20 ℃; for 0.5h; Inert atmosphere;

crocetindial; In methanol; at 20 ℃; for 4h; Time; Inert atmosphere;

Reference yield:

beta-carotene (7235-40-7) → (E)-β-ionone (79-77-6,14901-07-6) + 4,9,13-trimethyl-15-(2,6,6-trimethylcyclohex-1-enyl)pentadeca-2,4,6,8,10,12,14-heptaenal (640-49-3) + 2,6,6-trimethylcyclohex-1-enecarbaldehyde (432-25-7) + trans-β-apo-8'-carotenal (1107-26-2,4172-46-7) + 5,6-epoxy-trans-β-ionone (36340-49-5)

Guidance literature:

With tert.-butylhydroperoxide; μ-carbido-bis[(5,10,15,20-tetraphenyl-21H,23H-porphyrinato)iron(IV)]; In benzene; at 24.84 ℃; Reagent/catalyst; Kinetics;

DOI:10.1134/S0036024418110390

Reference yield:

all-trans-β-apo-8'-Carotenol (6541-41-9) → trans-β-apo-8'-carotenal (1107-26-2,4172-46-7)

Guidance literature:

With manganese(IV) oxide; In 1,2-dichloro-ethane; at 25 - 30 ℃; for 10h; Solvent; Temperature; Inert atmosphere;

upstream raw materials:

beta-carotene

15-cis-8'-apo-β-caroten-8'-al

(2E,4E,6E)-8,8-dimethoxy-3,7-dimethyl-octa-2,4,6-trienal

Retinyltriphenylphosphonium Chloride

Downstream raw materials:

15-cis-8'-apo-β-caroten-8'-al

8'-β-apocarotenol pent-4-ynoate

(E)-β-ionone

Refernces

• 1、 Simonova,Zaitseva,Tyulyaeva, E. Yu.,Zdanovich,Koifman. "Kinetics of β-Carotene Oxidation in the Presence of Highly Active Forms of μ-Carbido Diiron(IV) Tetraphenylporphyrinate". . p. 2128 - 2134. Retrieved 2018/10/24.
• 2、 Zhang, Shaofeng,Liu, Yuan,Luo, Juan. "Synthesis of analogues of citranaxanthin and their activity in free radical scavenging". . p. 257 - 260. Retrieved 2016/07/06.