1-propanethiolato(bis(2-(diphenylphosphino)ethyl)phenylphosphine)palladium(II) tetrafluoroborate

Base Information

• Chemical Name: 1-propanethiolato(bis(2-(diphenylphosphino)ethyl)phenylphosphine)palladium(II) tetrafluoroborate
• CAS No.: 493038-37-2
• Molecular Formula: BF₄*C₃₇H₄₀P₃PdS
• Molecular Weight: 802.936
• Mol file: 493038-37-2.mol

Synonyms:

Chemical Property of 1-propanethiolato(bis(2-(diphenylphosphino)ethyl)phenylphosphine)palladium(II) tetrafluoroborate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-propanethiolato(bis(2-(diphenylphosphino)ethyl)phenylphosphine)palladium(II) tetrafluoroborate

There total 1 articles about 1-propanethiolato(bis(2-(diphenylphosphino)ethyl)phenylphosphine)palladium(II) tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

1-thiopropane (107-03-9) + acetonitrile(bis(2-(diphenylphosphino)ethyl)phenylphosphine)palladium(II) tetrafluoroborate → 1-propanethiolato(bis(2-(diphenylphosphino)ethyl)phenylphosphine)palladium(II) tetrafluoroborate (493038-37-2)

Guidance literature:

With NaOH; In ethanol; water; acetonitrile; under N2; ligand added dropwise to soln. of Pd complex (molar ratio 1.6:1) in MeCN; EtOH and aq. NaOH added; filtered; water added to filtrate; crystals collected by filtration; recrystd. from CH2Cl2 by adding EtOH and water; elem. anal.;

DOI:10.1016/S0020-1693(02)00981-7

Reference yield:

1-propanethiolato(bis(2-(diphenylphosphino)ethyl)phenylphosphine)palladium(II) tetrafluoroborate (493038-37-2) + tetrabutyl-ammonium chloride (1112-67-0) → chloro(bis(2-(diphenylphosphino)ethyl)phenylphosphine)palladium(II)(1+) (47805-97-0)

Guidance literature:

In chloroform; under N2; react. of Pd complex with large excess of Bu4NCl in CHCl3; monitored by (31)P NMR spectra; Kinetics;

DOI:10.1016/S0020-1693(02)00981-7

Reference yield:

1-propanethiolato(bis(2-(diphenylphosphino)ethyl)phenylphosphine)palladium(II) tetrafluoroborate (493038-37-2) + tetra-(n-butyl)ammonium iodide (311-28-4) → iodo(bis(2-(diphenylphosphino)ethyl)phenylphosphine)palladium(II)(1+) (773788-18-4)

Guidance literature:

In chloroform; under N2; react. of Pd complex with large excess of Bu4NI in CHCl3; monitored by (31)P NMR spectra; Kinetics;

DOI:10.1016/S0020-1693(02)00981-7

upstream raw materials:

1-thiopropane

Downstream raw materials:

chloro(bis(2-(diphenylphosphino)ethyl)phenylphosphine)palladium(II)⁽¹⁺⁾

iodo(bis(2-(diphenylphosphino)ethyl)phenylphosphine)palladium(II)⁽¹⁺⁾