C5Me5Ru(PPh3)(η(3)-PhCHCHC=CPhCCPh)

Base Information

• Chemical Name: C5Me5Ru(PPh3)(η(3)-PhCHCHC=CPhCCPh)
• CAS No.: 193759-05-6
• Molecular Formula: C₅₂H₄₇PRu
• Molecular Weight: 803.989
• Mol file: 193759-05-6.mol

Synonyms:

Chemical Property of C5Me5Ru(PPh3)(η(3)-PhCHCHC=CPhCCPh)

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of C5Me5Ru(PPh3)(η(3)-PhCHCHC=CPhCCPh)

There total 1 articles about C5Me5Ru(PPh3)(η(3)-PhCHCHC=CPhCCPh) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

(η(5)-C5Me5)RuCl(PPh3)(=C=CHPh) (182556-90-7) + phenylacetylene (536-74-3) → C5Me5Ru(PPh3)(η(3)-PhCHCHC=CPhCCPh) (193759-05-6,416901-49-0)

Guidance literature:

With Et₃N; In dichloromethane; inert atmosphere; stirring (room temp., 24 h); evapn. (vac.), C6H6 addn., filtering, evapn. (vac.), washing (Et2O, hexanes); elem. anal.;

DOI:10.1021/om970366t

Reference yield:

C5Me5Ru(PPh3)(η(3)-PhCHCHC=CPhCCPh) (193759-05-6,416901-49-0) + ethenetetracarbonitrile (670-54-2) → C5(CH3)5RuP(C6H5)3C(CHCHC6H5)CC6H5C(CC6H5C(CN)2C(CN)CN) (389136-39-4)

Guidance literature:

In benzene; (N2); addn. of alkene to a soln. of ruthenium complex in C6H6, stirring for 30 min at room temp.; evapn., extn. with THF, preparative TLC (acetone/hexane 3:7); elem. anal.;

DOI:10.1039/b105131h

upstream raw materials:

(η(5)-C5Me5)RuCl(PPh3)(=C=CHPh)

phenylacetylene

Downstream raw materials:

C₅(CH₃)5RuP(C₆H₅)3C(CHCHC₆H₅)CC₆H₅C(CC₆H₅C(CN)2C(CN)CN)