titanocene(trifluorobenzoylacetone^(1-))ClO₄

Base Information

• Chemical Name: titanocene(trifluorobenzoylacetone^(1-))ClO₄
• CAS No.: 1151809-37-8
• Molecular Formula: C₂₀H₁₆F₃O₂Ti*ClO₄
• Molecular Weight: 492.672
• Mol file: 1151809-37-8.mol

Synonyms:

Chemical Property of titanocene(trifluorobenzoylacetone^(1-))ClO₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of titanocene(trifluorobenzoylacetone^(1-))ClO₄

There total 2 articles about titanocene(trifluorobenzoylacetone^(1-))ClO₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

bis(cyclopentadienyl)titanium dichloride (1271-19-8) + 1-Phenyl-4,4,4-trifluorobutane-1,3-dione (326-06-7) + silver perchlorate → titanocene(trifluorobenzoylacetone(1-))ClO4 (1151809-37-8)

Guidance literature:

With H₂O; In tetrahydrofuran; byproducts: AgCl; (N2); titanocene dichloride stirred in H2O/THF for 30 min; cooled in icebath; aq. AgClO4 added while shielded from light; filtered; trifluorobe nzoylacetone (disssolved in 4°C THF) added dropwise; stirred for 30 min; pptd. after 7 d; washed with H2O, and Et2O; recrystd. from CH2Cl2/hexane; elem. anal.;

DOI:10.1016/j.poly.2008.12.060

Reference yield:

bis(cyclopentadienyl)titanium dichloride (1271-19-8) + 1,1,1-trifluoro-4-hydroxy-4-phenyl-but-3-en-2-one (66929-54-2) + silver perchlorate → titanocene(trifluorobenzoylacetone(1-))ClO4 (1151809-37-8)

Guidance literature:

In tetrahydrofuran; water; byproducts: AgCl;

DOI:10.1016/j.electacta.2010.08.086

upstream raw materials:

bis(cyclopentadienyl)titanium dichloride

1-Phenyl-4,4,4-trifluorobutane-1,3-dione

1,1,1-trifluoro-4-hydroxy-4-phenyl-but-3-en-2-one