[Ru(II)(1,4,7-trithiacyclononane)(2-phenylazopyridine)(Cl)](ClO₄)

Base Information

• Chemical Name: [Ru(II)(1,4,7-trithiacyclononane)(2-phenylazopyridine)(Cl)](ClO₄)
• CAS No.: 1350610-19-3
• Molecular Formula: C₁₇H₂₁ClN₃RuS₃*ClO₄
• Molecular Weight: 599.545

Synonyms:

Chemical Property of [Ru(II)(1,4,7-trithiacyclononane)(2-phenylazopyridine)(Cl)](ClO₄)

Chemical Property:

Purity/Quality:

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Technology Process of [Ru(II)(1,4,7-trithiacyclononane)(2-phenylazopyridine)(Cl)](ClO₄)

There total 1 articles about [Ru(II)(1,4,7-trithiacyclononane)(2-phenylazopyridine)(Cl)](ClO₄) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

2-(phenylazo)pyridine (2569-57-5) + [(1,4,7-trithiacyclononane)RuII(DMSO)Cl2] + sodium perchlorate → [Ru(II)(1,4,7-trithiacyclononane)(2-phenylazopyridine)(Cl)](ClO4) (1350610-19-3)

Guidance literature:

In ethanol; (N2) 2-phenylazopyridine was added to soln. Ru complex in EtOH, heated under reflux for 5 h; solvent was removed in vacuo, residue was dissolved in MeCN, aq. soln. NaClO4 was added, ppt. was filtered off, washed with ice-cold water and dried in vacuo over P4O10, column chromy. on silica (CH2Cl2-MeCN 5:1); elem. anal.;

DOI:10.1039/c1dt10761e

Reference yield: 82.0%

[Ru(II)(1,4,7-trithiacyclononane)(2-phenylazopyridine)(Cl)](ClO4) (1350610-19-3) + sodium perchlorate + acetonitrile (75-05-8,26809-02-9) → [Ru(II)(1,4,7-trithiacyclononane)(2-phenylazopyridine)(MeCN)](ClO4)2

Guidance literature:

With AgNO₃; In water; acetonitrile; byproducts: AgCl; Ru complex in MeCN-H2O (1:1) was heated at reflux for 10 min, AgNO3 was added, heated for 4 h; soln. was cooled to room temp., filtered and concd., aq. soln. NaClO4 was added, ppt. was filtered off, washed with ice-cold water and dried over P4O10; elem. anal.;

DOI:10.1039/c1dt10761e

Reference yield:

[Ru(II)(1,4,7-trithiacyclononane)(2-phenylazopyridine)(Cl)](ClO4) (1350610-19-3) → [Ru(II)(1,4,7-trithiacyclononane)(2-phenylazopyridine)(NO)](ClO4)3

Guidance literature:

Multi-step reaction with 3 steps

1: AgNO₃ / acetonitrile; water

2: water

3: HClO₄ / nitric acid

With AgNO₃; HClO₄; In water; nitric acid; acetonitrile;

DOI:10.1039/c1dt10761e

upstream raw materials:

2-(phenylazo)pyridine

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