(1R)-1,2,3,4,4a,4bα,5,6,7,8,10,10aα-Dodecahydro-1,4aβ-dimethyl-7α-(1-methylethyl)-1α-phenanthrenecarboxylic acid methyl ester

Base Information

Chemical Name:(1R)-1,2,3,4,4a,4bα,5,6,7,8,10,10aα-Dodecahydro-1,4aβ-dimethyl-7α-(1-methylethyl)-1α-phenanthrenecarboxylic acid methyl ester
CAS No.:33892-12-5
Molecular Formula:C₂₁H₃₄O₂
Molecular Weight:318.5
Hs Code.:
Mol file:33892-12-5.mol

Synonyms:

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Chemical Property of (1R)-1,2,3,4,4a,4bα,5,6,7,8,10,10aα-Dodecahydro-1,4aβ-dimethyl-7α-(1-methylethyl)-1α-phenanthrenecarboxylic acid methyl ester

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Technology Process of (1R)-1,2,3,4,4a,4bα,5,6,7,8,10,10aα-Dodecahydro-1,4aβ-dimethyl-7α-(1-methylethyl)-1α-phenanthrenecarboxylic acid methyl ester

There total 1 articles about (1R)-1,2,3,4,4a,4bα,5,6,7,8,10,10aα-Dodecahydro-1,4aβ-dimethyl-7α-(1-methylethyl)-1α-phenanthrenecarboxylic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 186581-53-3,908094-01-9,334-88-3
diazomethane

: 19407-36-4
13αH-abieten-(7)-oic acid-(18)

: 33892-12-5,33892-13-6,67893-02-1
13β-Abieten-(7)-saeure-(18)-methylester

Guidance literature:: DOI:10.1021/jo01258a005

Reference yield:

: 33892-12-5,33892-13-6,67893-02-1
13β-Abieten-(7)-saeure-(18)-methylester

: 7,8-Dioxo-7,8-seco-13β-abietan-18-saeure-methylester

Guidance literature:: Multi-step reaction with 2 steps

1: OsO₄, Py

2: Pb(OAc)4

With pyridine; lead(IV) acetate; osmium(VIII) oxide;
DOI:10.1021/jo01258a005