C₄₈H₃₅N₅NiO₂

Base Information

• Chemical Name: C₄₈H₃₅N₅NiO₂
• CAS No.: 650599-08-9
• Molecular Formula: C₄₈H₃₅N₅NiO₂
• Molecular Weight: 772.528
• Mol file: 650599-08-9.mol

Synonyms:

Chemical Property of C₄₈H₃₅N₅NiO₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₄₈H₃₅N₅NiO₂

There total 2 articles about C₄₈H₃₅N₅NiO₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Ni{(C4H2N)4(C(C6H4CH3))4} (58188-46-8) → C48H35N5NiO2 (650599-08-9)

Guidance literature:

With lithium nitrate; acetic anhydride; acetic acid; In chloroform;

DOI:10.1021/ol2020658

Reference yield:

meso-tetrakis(p-tolyl)porphyrinatonickel(II) (58188-46-8) + lithium nitrate → [Ni(C20H7N4(C6H4CH3)4NO2)] (650599-08-9)

Guidance literature:

With acetic acid; acetic anhydride; In chloroform; acetic acid; soln. of LiNO3 in acetic acid/acetanhydride added to warm soln. of nickel tetraaryl porphyrin in CHCl3, stirred for 1.5 h; mixt. neutralized with aq. NaHCO3, washed with water, organic phase sepd. and evapd., crystn. from CH2Cl2-MeOH;

DOI:10.1021/ic035203d

Reference yield:

[Ni(C20H7N4(C6H4CH3)4NO2)] (650599-08-9) → [Ni(C20H7N4(C6H4CH3)3(C6H3(CH3)NH))] (650598-92-8)

Guidance literature:

With triethyl phosphite; In further solvent(s); degassed soln. of nickel 2-nitro-meso-tetraarylporphyrin in 1,2-dichlorobenzene containing triethyl phosphite was heated under Ar at 155°C for 3 h; react. mixt. chromd. (silica gel, hexane/dichloromethane), crystn. from CH2Cl2/MeOH;

DOI:10.1021/ic035203d

upstream raw materials:

meso-tetrakis(p-tolyl)porphyrinatonickel(II)

Ni{(C₄H₂N)4(C(C₆H₄CH₃))4}

Downstream raw materials:

[Ni(C₂₀H₇N₄(C₆H₄CH₃)3(C₆H₃(CH₃)NH))]

[Ni(C₂₀H₆N₄(C₆H₄CH₃)3(C₆H₃(CH₃)NH)CHO)]

Ni(II)-2-NH₂-TTP