bis-[(3,4,5-trimethoxybenzyl)cyclopentadienyl]vanadium(IV) dichloride

Base Information

• Chemical Name: bis-[(3,4,5-trimethoxybenzyl)cyclopentadienyl]vanadium(IV) dichloride
• CAS No.: 1158001-40-1
• Molecular Formula: C₃₀H₃₄Cl₂O₆V
• Molecular Weight: 612.444
• Mol file: 1158001-40-1.mol

Synonyms:

Chemical Property of bis-[(3,4,5-trimethoxybenzyl)cyclopentadienyl]vanadium(IV) dichloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of bis-[(3,4,5-trimethoxybenzyl)cyclopentadienyl]vanadium(IV) dichloride

There total 1 articles about bis-[(3,4,5-trimethoxybenzyl)cyclopentadienyl]vanadium(IV) dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.2%

Li(1+)*C5H4CH2C6H2(OCH3)3(1-)=Li(C5H4CH2C6H2(OCH3)3) + vanadiumtetrachloride (7632-51-1) → bis-[(3,4,5-trimethoxybenzyl)cyclopentadienyl]vanadium(IV) dichloride (1158001-40-1)

Guidance literature:

In tetrahydrofuran; byproducts: LiCl; (Ar or N2, Schlenk) VCl4 was added slowly to a soln. of Li-compound in THF at -78°C, the soln. was refluxed for 20 h at 88°C, allowed to return to room temp., cooled to -78°C; ppt. was filtered, washed with THF and small CHCl3, dissolved in CHCl3, filtered, the solvent was removed under reduced pressure; elem. anal.;

DOI:10.1016/j.jorganchem.2008.12.033

upstream raw materials:

vanadiumtetrachloride