di-2-pyridyl ketone Schiff base of S-benzyldithiocarbazate

Base Information

• Chemical Name: di-2-pyridyl ketone Schiff base of S-benzyldithiocarbazate
• CAS No.: 615554-51-3
• Molecular Formula: C₁₉H₁₆N₄S₂
• Molecular Weight: 364.495
• Mol file: 615554-51-3.mol

Synonyms:

Chemical Property of di-2-pyridyl ketone Schiff base of S-benzyldithiocarbazate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of di-2-pyridyl ketone Schiff base of S-benzyldithiocarbazate

There total 1 articles about di-2-pyridyl ketone Schiff base of S-benzyldithiocarbazate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.71%

2,2'-dipyridyl ketone (19437-26-4) + S-benzyldithiocarbazate (13331-31-2) → di-2-pyridyl ketone Schiff base of S-benzyldithiocarbazate (615554-51-3)

Guidance literature:

In ethanol; for 1h; Reflux;

DOI:10.1039/c2dt12387h

Reference yield: 64.0%

iron(II) perchlorate hexahydrate + di-2-pyridyl ketone Schiff base of S-benzyldithiocarbazate (615554-51-3) → [iron(II)(di-2-pyridyl ketone S-benzyldithiocarbazate(-H))2]*0.5H2O

Guidance literature:

With triethylamine; In ethanol; soln. of HPKSBC (2 equiv.) purged with N2 for 10 min, triethylamine (2 equiv.) added, Fe(ClO4)2*6H2O added with stirring, refluxed for 30 min under N2, cooled to room temp.; ppt. filtered off, washed with EtOH, Et2O; elem. anal.;

DOI:10.1039/c2dt12387h

Reference yield: 48.0%

iron perchlorate hexahydrate + di-2-pyridyl ketone Schiff base of S-benzyldithiocarbazate (615554-51-3) → [iron(III)(di-2-pyridyl ketone S-benzyldithiocarbazate(-H))2](perchlorate)*2.5H2O

Guidance literature:

With triethylamine; In ethanol; Fe(ClO4)3*6H2O added to hot soln. of HPKSBC (2 equiv.), triethylamine (2equiv.) added, refluxed for 30 min; hot filtered, filtrate cooled to room temp., kept in refrigerator overnight, filtered, washed with Et2O; elem. anal.;

DOI:10.1039/c2dt12387h

upstream raw materials:

2,2'-dipyridyl ketone

S-benzyldithiocarbazate