(R,S)-propargylglycinato(bistriphenylphosphan)palladium(II) tetrafluoroborate

Base Information

• Chemical Name: (R,S)-propargylglycinato(bistriphenylphosphan)palladium(II) tetrafluoroborate
• CAS No.: 944920-46-1
• Molecular Formula: BF₄*C₄₁H₃₆NO₂P₂Pd
• Molecular Weight: 829.914
• Mol file: 944920-46-1.mol

Synonyms:

Chemical Property of (R,S)-propargylglycinato(bistriphenylphosphan)palladium(II) tetrafluoroborate

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

Technology Process of (R,S)-propargylglycinato(bistriphenylphosphan)palladium(II) tetrafluoroborate

There total 1 articles about (R,S)-propargylglycinato(bistriphenylphosphan)palladium(II) tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

di-μ-chloro-bis[bis(triphenylphosphine)palladium(II)] tetrafluoroborate + D,L-propargylglycine (50428-03-0) → (R,S)-propargylglycinato(bistriphenylphosphan)palladium(II) tetrafluoroborate (944920-46-1)

Guidance literature:

With sodium methylate; In methanol; dichloromethane; byproducts: NaCl; Pd compd. dissolved in CH2Cl2 at -78°C; soln. of MeONa in MeOH added to suspn. of org. compd. in MeOH, this mixt. added dropwise to soln.of complex at -78°C, stirred for 24 h at this temp., cold Et2O a dded dropwise; centrifuged in cold, washed with cold ether, stored at cold, dried in vac. at -50°C; elem. anal.;

DOI:10.1002/zaac.200600158

upstream raw materials:

D,L-propargylglycine