trans-7-hexyl-2-phenyl-3-(triethylsiloxy)oxepane

Base Information

Chemical Name:trans-7-hexyl-2-phenyl-3-(triethylsiloxy)oxepane
CAS No.:128372-43-0
Molecular Formula:C₂₄H₄₂O₂Si
Molecular Weight:390.682
Hs Code.:

Synonyms:

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Chemical Property of trans-7-hexyl-2-phenyl-3-(triethylsiloxy)oxepane

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Technology Process of trans-7-hexyl-2-phenyl-3-(triethylsiloxy)oxepane

There total 17 articles about trans-7-hexyl-2-phenyl-3-(triethylsiloxy)oxepane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 710-04-3
6-hexyltetrahydro-2H-pyran-2-one

: 128372-43-0
trans-7-hexyl-2-phenyl-3-(triethylsiloxy)oxepane

Guidance literature:: Multi-step reaction with 8 steps

1: 1) butyllithium / 1) -78 deg C, 30 min, THF, 2a) -78 deg C, 1 h, 2b) 0 deg C, 2 h

2: 1) LDA / 1) -78 deg C, 30 min, 2) -78 deg C -> room temperature

3: methanesulphonyl azide, triethylamine / ethanol / 60 h / Ambient temperature

4: 81 percent / hydrochloric acid / tetrahydrofuran / 0.08 h

5: 73 percent / dirhodium tetraacetate / benzene / 0.08 h / Heating

6: 97 percent / cerium trichloride, sodium borohydride / methanol / 0.08 h / Ambient temperature

7: 61 percent / 2,6-dimethylpyridine / CH₂Cl₂ / 0.5 h / Ambient temperature

8: 1) magnesium, zinc bromide / 1) THF, room temperature, 30 min, 2) room temperature, overnight

With 2,6-dimethylpyridine; hydrogenchloride; dirhodium tetraacetate; sodium tetrahydroborate; n-butyllithium; cerium(III) chloride; magnesium; triethylamine; Methanesulfonyl azide; zinc dibromide; lithium diisopropyl amide; In tetrahydrofuran; methanol; ethanol; dichloromethane; benzene;

Reference yield:

: 1-Benzenesulfonyl-6-hydroxy-dodecan-2-one

: 128372-43-0
trans-7-hexyl-2-phenyl-3-(triethylsiloxy)oxepane

Guidance literature:: Multi-step reaction with 7 steps

1: 1) LDA / 1) -78 deg C, 30 min, 2) -78 deg C -> room temperature

2: methanesulphonyl azide, triethylamine / ethanol / 60 h / Ambient temperature

3: 81 percent / hydrochloric acid / tetrahydrofuran / 0.08 h

4: 73 percent / dirhodium tetraacetate / benzene / 0.08 h / Heating

5: 97 percent / cerium trichloride, sodium borohydride / methanol / 0.08 h / Ambient temperature

6: 61 percent / 2,6-dimethylpyridine / CH₂Cl₂ / 0.5 h / Ambient temperature

7: 1) magnesium, zinc bromide / 1) THF, room temperature, 30 min, 2) room temperature, overnight

With 2,6-dimethylpyridine; hydrogenchloride; dirhodium tetraacetate; sodium tetrahydroborate; cerium(III) chloride; magnesium; triethylamine; Methanesulfonyl azide; zinc dibromide; lithium diisopropyl amide; In tetrahydrofuran; methanol; ethanol; dichloromethane; benzene;

Reference yield:

: 132834-87-8
7-hexyl-2-phenylsulphonyloxepan-3-ol

: 128372-43-0
trans-7-hexyl-2-phenyl-3-(triethylsiloxy)oxepane

Guidance literature:: Multi-step reaction with 2 steps

1: 61 percent / 2,6-dimethylpyridine / CH₂Cl₂ / 0.5 h / Ambient temperature

2: 1) magnesium, zinc bromide / 1) THF, room temperature, 30 min, 2) room temperature, overnight

With 2,6-dimethylpyridine; magnesium; zinc dibromide; In dichloromethane;