9,9'-(2-((4-phenyl-1,2,3-triazol-1-yl)methyl)biphenyl-4,4'-diyl)biscarbazole

Base Information

Chemical Name:9,9'-(2-((4-phenyl-1,2,3-triazol-1-yl)methyl)biphenyl-4,4'-diyl)biscarbazole
CAS No.:1246290-86-7
Molecular Formula:C₄₅H₃₁N₅
Molecular Weight:641.775
Hs Code.:

Synonyms:

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Chemical Property of 9,9'-(2-((4-phenyl-1,2,3-triazol-1-yl)methyl)biphenyl-4,4'-diyl)biscarbazole

Chemical Property:

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Technology Process of 9,9'-(2-((4-phenyl-1,2,3-triazol-1-yl)methyl)biphenyl-4,4'-diyl)biscarbazole

There total 10 articles about 9,9'-(2-((4-phenyl-1,2,3-triazol-1-yl)methyl)biphenyl-4,4'-diyl)biscarbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

: 1246290-95-8
9,9'-((2-azidomethyl)biphenyl-4,4'-diyl)biscarbazole

: 536-74-3
phenylacetylene

: 1246290-86-7
9,9'-(2-((4-phenyl-1,2,3-triazol-1-yl)methyl)biphenyl-4,4'-diyl)biscarbazole

Guidance literature:: With copper(ll) sulfate pentahydrate; sodium L-ascorbate; In tetrahydrofuran; water; at 100 ℃; for 15h;
DOI:10.1039/c0nj00091d

Reference yield:

: 86-74-8,105184-46-1,97960-57-1
9H-carbazole

: 1246290-86-7
9,9'-(2-((4-phenyl-1,2,3-triazol-1-yl)methyl)biphenyl-4,4'-diyl)biscarbazole

Guidance literature:: Multi-step reaction with 7 steps

1.1: copper(l) iodide; potassium phosphate; trans-1,2-Diaminocyclohexane / toluene / 24 h / 110 °C / Inert atmosphere; sealed tube

2.1: n-butyllithium / tetrahydrofuran / Inert atmosphere; Cooling with acetone-dry ice

2.2: 20 °C / Inert atmosphere; Cooling with acetone-dry ice

3.1: hydrogenchloride; water / 0.5 h / Inert atmosphere

4.1: tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; sodium carbonate; 2-(dicyclohexylphosphino)-2'-methylbiphenyl / toluene / 24 h / 110 °C / Inert atmosphere; sealed tube

5.1: N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) / tetrachloromethane / 10 h / Reflux

6.1: sodium azide / N,N-dimethyl-formamide / 10 h / 70 °C

7.1: copper(ll) sulfate pentahydrate; sodium L-ascorbate / tetrahydrofuran; water / 15 h / 100 °C

With hydrogenchloride; potassium phosphate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; N-Bromosuccinimide; copper(l) iodide; n-butyllithium; sodium azide; copper(ll) sulfate pentahydrate; 2,2'-azobis(isobutyronitrile); trans-1,2-Diaminocyclohexane; water; sodium carbonate; sodium L-ascorbate; 2-(dicyclohexylphosphino)-2'-methylbiphenyl; In tetrahydrofuran; tetrachloromethane; water; N,N-dimethyl-formamide; toluene;
DOI:10.1039/c0nj00091d

Reference yield:

: 699119-26-1
[4-(9H-carbazol-9-yl)-2-methylphenyl]boronic acid

: 1246290-86-7
9,9'-(2-((4-phenyl-1,2,3-triazol-1-yl)methyl)biphenyl-4,4'-diyl)biscarbazole

Guidance literature:: Multi-step reaction with 4 steps

1: tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; sodium carbonate; 2-(dicyclohexylphosphino)-2'-methylbiphenyl / toluene / 24 h / 110 °C / Inert atmosphere; sealed tube

2: N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) / tetrachloromethane / 10 h / Reflux

3: sodium azide / N,N-dimethyl-formamide / 10 h / 70 °C

4: copper(ll) sulfate pentahydrate; sodium L-ascorbate / tetrahydrofuran; water / 15 h / 100 °C

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; N-Bromosuccinimide; sodium azide; copper(ll) sulfate pentahydrate; 2,2'-azobis(isobutyronitrile); sodium carbonate; sodium L-ascorbate; 2-(dicyclohexylphosphino)-2'-methylbiphenyl; In tetrahydrofuran; tetrachloromethane; water; N,N-dimethyl-formamide; toluene;
DOI:10.1039/c0nj00091d