N,N-bis[2-(2-pyridyl)ethyl]hydroxylamine

Base Information

• Chemical Name: N,N-bis[2-(2-pyridyl)ethyl]hydroxylamine
• CAS No.: 6965-67-9
• Molecular Formula: C₁₄H₁₇N₃O
• Molecular Weight: 243.308
• NSC Number: 63343
• DSSTox Substance ID: DTXSID90289746
• Nikkaji Number: J1.978.261A
• Wikidata: Q82027197
• ChEMBL ID: CHEMBL1702572
• Mol file: 6965-67-9.mol

Synonyms:NSC63343;MLS002693431;6965-67-9;N,N-bis[2-(2-pyridyl)ethyl]hydroxylamine;NCIOpen2_002634;CHEMBL1702572;SCHEMBL11586559;DTXSID90289746;HMS3088F10;NSC-63343;bis(2-{pyridyl-2-yl}ethyl)hydroxylamine;bis(2-pyridine-2-ylethyl)hydroxyl-amine;SMR001559386;N,N-bis[2-(2-pyridinyl)ethyl]hydroxylamine;Pyridine, 2,2'-[(hydroxyimino)di-2,1-ethanediyl]bis-

Chemical Property of N,N-bis[2-(2-pyridyl)ethyl]hydroxylamine

Chemical Property:

• Vapor Pressure: 4.22E-08mmHg at 25°C
• Boiling Point: 428.4°C at 760 mmHg
• Flash Point: 212.9°C
• Density: 1.174g/cm³
• XLogP3: 1.6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 6
• Exact Mass: 243.137162174
• Heavy Atom Count: 18
• Complexity: 203

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=NC(=C1)CCN(CCC2=CC=CC=N2)O

Technology Process of N,N-bis[2-(2-pyridyl)ethyl]hydroxylamine

There total 2 articles about N,N-bis[2-(2-pyridyl)ethyl]hydroxylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

2-vinylpyridine (100-69-6,25014-15-7,27476-03-5,329041-71-6) → N,N-bis(2-(pyridin-2-yl)ethyl)hydroxylamine (6965-67-9)

Guidance literature:

With hydroxylamine hydrochloride; for 15h;

Reference yield:

→ N,N-bis(2-(pyridin-2-yl)ethyl)hydroxylamine (6965-67-9)

Guidance literature:

2-Vinyl-pyridin, Hydroxylamin-hydrochlorid;

DOI:10.1021/jo01030a523

Reference yield: 80.0%

N,N-bis(2-(pyridin-2-yl)ethyl)hydroxylamine (6965-67-9) + trimethylaluminum (75-24-1) + toluene (108-88-3,15644-74-3,16713-13-6) → [AlMe2(N,N-bis[2-(pyrid-2-yl)ethyl]hydroxylamine(-1H))*2AlMe3]

Guidance literature:

In toluene; byproducts: CH4; (Ar); Al(CH3)3 added at ambient temp. to a suspn. of ligand, stirred for12 h; filtered, concd., crystd. by layering pentane onto the toluene soln. for12 h; elem. anal.;

DOI:10.1039/c0dt00334d

upstream raw materials:

2-vinylpyridine

Downstream raw materials:

N,N-bis(2-(pyridin-2-yl)ethyl)benzamide