Ho[OC(Bun)NPh]3

Base Information

• Chemical Name: Ho[OC(Bun)NPh]3
• CAS No.: 394210-80-1
• Molecular Formula: C₃₃H₄₂HoN₃O₃
• Molecular Weight: 693.645
• Mol file: 394210-80-1.mol

Synonyms:

Chemical Property of Ho[OC(Bun)NPh]3

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of Ho[OC(Bun)NPh]3

There total 1 articles about Ho[OC(Bun)NPh]3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

n-butyllithium (109-72-8,29786-93-4) + (C5H4CH3)HoCl2(THF)3 (206120-18-5) + phenyl isocyanate (103-71-9) → Ho[OC(Bun)NPh]3 (394210-80-1) + [(C5H4CH3)2HoOC(Bun)NPh]2 (394210-81-2)

Guidance literature:

In tetrahydrofuran; under Ar to soln. Cp'HoCl2(THF)3 in THF was added n-BuLi at -30°C, stirred for 3 h, allowed to warm to 0°C, stirred for 1.5 h, cooled to -30°C, PhNCO was added, stirred for 3 h, warmed to room temp., stirred for 48 h; solvent was removed, residue was extd. with cold toluene, concd. - Ho(OC(Bun)NPh)3; hexane was diffused into filtrate - (Cp'2HoOC(Bun)NPh)2; elem. anal.;

DOI:10.1021/om010346y

upstream raw materials:

n-butyllithium

(C₅H₄CH₃)HoCl₂(THF)3

phenyl isocyanate