trans-[HFe(bis((diethylphosphino)methyl)methylamine)(bis(dimethylphosphino)methane)(acetonitrile)](BPh₄)

Base Information

• Chemical Name: trans-[HFe(bis((diethylphosphino)methyl)methylamine)(bis(dimethylphosphino)methane)(acetonitrile)](BPh₄)
• CAS No.: 852529-17-0
• Molecular Formula: C₁₈H₄₅FeN₂P₄*C₂₄H₂₀B
• Molecular Weight: 788.545

Synonyms:

Chemical Property of trans-[HFe(bis((diethylphosphino)methyl)methylamine)(bis(dimethylphosphino)methane)(acetonitrile)](BPh₄)

Chemical Property:

Purity/Quality:

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Technology Process of trans-[HFe(bis((diethylphosphino)methyl)methylamine)(bis(dimethylphosphino)methane)(acetonitrile)](BPh₄)

There total 1 articles about trans-[HFe(bis((diethylphosphino)methyl)methylamine)(bis(dimethylphosphino)methane)(acetonitrile)](BPh₄) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 23.0%

[FeHCl(Et2PCH2N(Me)CH2PEt2)(dmpm)] (852529-15-8) + sodium tetraphenyl borate (143-66-8) → trans-[HFe(bis((diethylphosphino)methyl)methylamine)(bis(dimethylphosphino)methane)(acetonitrile)](BPh4) (852529-17-0)

Guidance literature:

In acetonitrile; under Ar or N2; Fe complex and NaBPh4 (excess) added to MeCN; stirred for 2 h; pptd. by addition of H2O; ppt. washed with ether; crystd. from MeCN-ether at -15°C; elem. anal.;

DOI:10.1021/om050071c

Reference yield:

[D3]acetonitrile (2206-26-0) + trans-[HFe(bis((diethylphosphino)methyl)methylamine)(bis(dimethylphosphino)methane)(acetonitrile)](BPh4) (852529-17-0) → trans-[HFe(bis((diethylphosphino)methyl)methylamine)(bis(dimethylphosphino)methane)(acetonitrile-d3)](BPh4)

Guidance literature:

In [D₃]acetonitrile; byproducts: MeCN; under Ar or N2; Fe complex dissolved in CD3CN at 23°C; not isolated; monitored by (1)H NMR spectra;

DOI:10.1021/om050071c

upstream raw materials:

[FeHCl(Et₂PCH₂N(Me)CH₂PEt₂)(dmpm)]

sodium tetraphenyl borate

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