[((C₆H₅)NCH(2-O-C₆H₂-(t-Bu)2-3,5)3ThCl]

Base Information

• Chemical Name: [((C₆H₅)NCH(2-O-C₆H₂-(t-Bu)2-3,5)3ThCl]
• CAS No.: 929642-68-2
• Molecular Formula: C₆₃H₇₈ClN₃O₃Th
• Molecular Weight: 1192.82
• Mol file: 929642-68-2.mol

Synonyms:

Chemical Property of [((C₆H₅)NCH(2-O-C₆H₂-(t-Bu)2-3,5)3ThCl]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [((C₆H₅)NCH(2-O-C₆H₂-(t-Bu)2-3,5)3ThCl]

There total 1 articles about [((C₆H₅)NCH(2-O-C₆H₂-(t-Bu)2-3,5)3ThCl] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

ThCl4*3C4H8O + C6H5NCHC6H2(C(CH3)3)2O(1-)*Li(1+)=C6H5NCHC6H2(C(CH3)3)2OLi (929642-67-1) → [((C6H5)NCH(2-O-C6H2-(t-Bu)2-3,5)3ThCl] (929642-68-2)

Guidance literature:

In diethyl ether; byproducts: LiCl, THF; (N2); glovebox; soln. of Na salt of ligand (1 equiv.) in Et2O was added dropwise over 20 min to soln. of Th compd. in Et2O at -78°C; warmed to room temp. and stirred for 12 h; filtered; washed (Et2O); filtrate evapd. (vac.); dissolved in toluene; filtered; filtrate evapd. (vac.); hexane added; residue washed (hexane); crystd. (toluene/hexane, -30°C); elem. anal.;

DOI:10.1016/j.jorganchem.2006.10.071

upstream raw materials:

C₆H₅NCHC₆H₂(C(CH₃)3)2O^(1-)*Li⁽¹⁺⁾=C₆H₅NCHC₆H₂(C(CH₃)3)2OLi