PdP(C₆H₅)2C₆H₄CHNCH₂CH₂NHCH₂CH₂NH₂⁽²⁺⁾*ZnCl₄^(2-)=PdP(C₆H₅)2C₆H₄CHNCH₂CH₂NHCH₂CH₂NH₂ZnCl₄

Base Information

• Chemical Name: PdP(C₆H₅)2C₆H₄CHNCH₂CH₂NHCH₂CH₂NH₂⁽²⁺⁾*ZnCl₄^(2-)=PdP(C₆H₅)2C₆H₄CHNCH₂CH₂NHCH₂CH₂NH₂ZnCl₄
• CAS No.: 310871-61-5
• Molecular Formula: C₂₃H₂₆N₃PPd*Cl₄Zn
• Molecular Weight: 689.075
• Mol file: 310871-61-5.mol

Synonyms:

Chemical Property of PdP(C₆H₅)2C₆H₄CHNCH₂CH₂NHCH₂CH₂NH₂⁽²⁺⁾*ZnCl₄^(2-)=PdP(C₆H₅)2C₆H₄CHNCH₂CH₂NHCH₂CH₂NH₂ZnCl₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of PdP(C₆H₅)2C₆H₄CHNCH₂CH₂NHCH₂CH₂NH₂⁽²⁺⁾*ZnCl₄^(2-)=PdP(C₆H₅)2C₆H₄CHNCH₂CH₂NHCH₂CH₂NH₂ZnCl₄

There total 1 articles about PdP(C₆H₅)2C₆H₄CHNCH₂CH₂NHCH₂CH₂NH₂⁽²⁺⁾*ZnCl₄^(2-)=PdP(C₆H₅)2C₆H₄CHNCH₂CH₂NHCH₂CH₂NH₂ZnCl₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

trans-[PdCl2(o-diphenylphosphinobenzaldehyde)2] (310871-58-0,1008365-70-5) + {Zn(II)(diethylenetriamine)Cl}Cl (22470-27-5,37565-96-1) → PdCl2(P(C6H5)2C6H4CHN)2ZnClC2H4NHC2H4(1+) + PdP(C6H5)2C6H4CHNCH2CH2NHCH2CH2NH2(2+)*ZnCl4(2-)=PdP(C6H5)2C6H4CHNCH2CH2NHCH2CH2NH2ZnCl4 (310871-61-5)

Guidance literature:

In ethanol; a suspn. in ethanol was heated to reflux for 2 h; ppt. was filtered, recrystd. from CH3OH-Et2O; elem. anal.;

DOI:10.1016/S0020-1693(00)00181-X

Reference yield: 94.0%

ammonium hexafluorophosphate + PdP(C6H5)2C6H4CHNCH2CH2NHCH2CH2NH2(2+)*ZnCl4(2-)=PdP(C6H5)2C6H4CHNCH2CH2NHCH2CH2NH2ZnCl4 (310871-61-5) → PdP(C6H5)2C6H4CHNCH2CH2NHCH2CH2NH2(2+)*2PF6(1-)=PdP(C6H5)2C6H4CHNCH2CH2NHCH2CH2NH2(PF6)2

Guidance literature:

In acetonitrile; a suspn. of complex in CH3CN was treated with NH4PF6; filtered in hot, reduced in vol. H2O was added, standing in freezer forseveral h, recrystd. from CH3Cn-i-PrOH; elem. anal.;

DOI:10.1016/S0020-1693(00)00181-X

upstream raw materials:

trans-[PdCl₂(o-diphenylphosphinobenzaldehyde)2]

{Zn(II)(diethylenetriamine)Cl}Cl