[5,15-bis(3,5-di-tert-butylphenyl)-10-[4-(dipyrromethane-5-yl)phenyl]-20-mesitylporphinato]zinc(II)

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Chemical Name:[5,15-bis(3,5-di-tert-butylphenyl)-10-[4-(dipyrromethane-5-yl)phenyl]-20-mesitylporphinato]zinc(II)
CAS No.:573715-41-0
Molecular Formula:C₇₂H₇₄N₆Zn
Molecular Weight:1088.81
Hs Code.:

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Chemical Property of [5,15-bis(3,5-di-tert-butylphenyl)-10-[4-(dipyrromethane-5-yl)phenyl]-20-mesitylporphinato]zinc(II)

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Technology Process of [5,15-bis(3,5-di-tert-butylphenyl)-10-[4-(dipyrromethane-5-yl)phenyl]-20-mesitylporphinato]zinc(II)

There total 1 articles about [5,15-bis(3,5-di-tert-butylphenyl)-10-[4-(dipyrromethane-5-yl)phenyl]-20-mesitylporphinato]zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 5,15-bis(3,5-di-tert-butylphenyl)-10-[4-(dipyrromethane-5-yl)phenyl]-20-mesitylporphyrin

: 5970-45-6
zinc(II) acetate dihydrate

: 573715-41-0
[5,15-bis(3,5-di-tert-butylphenyl)-10-[4-(dipyrromethane-5-yl)phenyl]-20-mesitylporphinato]zinc(II)

Guidance literature:: In methanol; chloroform; a soln. of porphyrin in CHCl3 was treated with a soln. of Zn-salt in methanol, the mixt. was stirred overnight at room temp.; column chromy. (silica gel, CHCl3);
DOI:10.1021/ic026206d

Reference yield: 31.0%

: 573715-41-0
[5,15-bis(3,5-di-tert-butylphenyl)-10-[4-(dipyrromethane-5-yl)phenyl]-20-mesitylporphinato]zinc(II)

: 874-60-2
4-methyl-benzoyl chloride

: ((C₄H₉)2C₆H₃)2C₆H₂(CH₃)3C₂₀H₈C₆H₄CH(C₄H₃NH)C₄H₂NHCOC₆H₄CH₃N₄Zn

: 573715-39-6
[5,15-bis(3,5-di-tert-butylphenyl)-10-[4-(1,9-bis(4-methylbenzoyl)dipyrromethane-5-yl)phenyl]-20-mesitylporphinato]zinc(II)

Guidance literature:: With ethylmagnesium bromide; In tetrahydrofuran; toluene; a soln. of complex in toluene was treated with a soln. of C2H5MgBr in THF for 30 min, then p-toluoyl chloride was added, the mixt. was stirred for 45 min at room temp.; quenched with satd. aq. NH4Cl, ethyl acetate was added, the organic phase was washed with water and brine, dried (Na2SO4), the solvent was removed, chromd. on silica gel column (CH2Cl2-ethyl acetate; CHCl3);
DOI:10.1021/ic026206d