dichloro(ruthenocenyl)(2,4,6-triisopropylphenyl)silane

Base Information

Chemical Name:dichloro(ruthenocenyl)(2,4,6-triisopropylphenyl)silane
CAS No.:1187946-72-0
Molecular Formula:C₂₅H₃₂Cl₂RuSi
Molecular Weight:532.591
Hs Code.:

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Chemical Property of dichloro(ruthenocenyl)(2,4,6-triisopropylphenyl)silane

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Technology Process of dichloro(ruthenocenyl)(2,4,6-triisopropylphenyl)silane

There total 1 articles about dichloro(ruthenocenyl)(2,4,6-triisopropylphenyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

: 1287-13-4
bis(η⁵-cyclopentadienyl)ruthenium

: trichloro(2,4,6-triisopropylphenyl)silane

: 1187946-72-0
dichloro(ruthenocenyl)(2,4,6-triisopropylphenyl)silane

Guidance literature:: With (CH₃)3CLi; In tetrahydrofuran; pentane; (Ar); addn. of pentane soln. of (CH3)3CLi to soln. of ruthenium compd. in C4H8O at -78°C, stirring for 30 min at same temp., warming to room temp., addn. of soln. of silicon compd. in C4H8O at -78°C, stirring at same temp. for 30 min; warming to room temp., evapn., filtration through Celite with hexane, evapn. under reduced pressure, gel permeation liquid chromy. (toluene), elem. anal.;
DOI:10.1246/bcsj.82.793

Reference yield: 53.0%

: 1187946-72-0
dichloro(ruthenocenyl)(2,4,6-triisopropylphenyl)silane

: (E)-1,2-bis(ruthenocenyl)-1,2-bis(2,4,6-triisopropylphenyl)disilene

Guidance literature:: With lithium naphthalenide; In tetrahydrofuran; (Ar); addn. of soln. of lithium compd. in C4H8O to soln. of ruthenium compd. in C4H8O at -78°C, stirring for 30 min at same temp., warming to room temp.; evapn., extn. with hexane, filtration with Celite , evapn. under reduced pressure, elem. anal.;
DOI:10.1246/bcsj.82.793