Benzenamine, N-(2-furanylmethylene)-4-nitro-

Base Information

• Chemical Name: Benzenamine, N-(2-furanylmethylene)-4-nitro-
• CAS No.: 13533-24-9
• Molecular Formula: C11H8N2O3
• Molecular Weight: 216.196
• DSSTox Substance ID: DTXSID00470502
• Nikkaji Number: J1.883.415D
• Mol file: 13533-24-9.mol

Synonyms:13533-24-9;Benzenamine, N-(2-furanylmethylene)-4-nitro-;DTXSID00470502;AKOS003632425;N-(Furan-2-ylmethylene)-4-nitroaniline

Chemical Property of Benzenamine, N-(2-furanylmethylene)-4-nitro-

Chemical Property:

• XLogP3: 2.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 2
• Exact Mass: 216.05349212
• Heavy Atom Count: 16
• Complexity: 267

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=COC(=C1)C=NC2=CC=C(C=C2)[N+](=O)[O-]

Technology Process of Benzenamine, N-(2-furanylmethylene)-4-nitro-

There total 2 articles about Benzenamine, N-(2-furanylmethylene)-4-nitro- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

furfural (98-01-1) + 4-nitro-aniline (100-01-6,104810-17-5) → 2-furfurylidene-p-nitroaniline (13533-24-9)

Guidance literature:

sodium hydrogen sulfate; silica gel; at 58 - 60 ℃; for 0.0236111h; microwave irradiation;

Reference yield:

furfural (98-01-1) + 4-nitro-aniline (100-01-6,104810-17-5) → N-furanylmethylene-p-nitroaniline (13533-24-9)

Guidance literature:

With ethanol;

Reference yield: 32.0%

N-furanylmethylene-p-nitroaniline (13533-24-9) + 1H-cyclopropa[b]naphthalene (286-85-1) → 1-furan-2-yl-2-(4-nitro-phenyl)-2,3-dihydro-1H-benzo[f]isoindole

Guidance literature:

With tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)ytterbium; In chloroform; at 60 ℃; for 72h;

DOI:10.3987/COM-02-9697

upstream raw materials:

furfural

4-nitro-aniline

Downstream raw materials:

2-(4-hydroxy-anilino)-4-(4-nitro-anilino)-cyclopent-2-enone

furan-2-ylmethyl-(4-nitro-phenyl)-amine

Refernces

• 1、 Gopalakrishnan, Mannathusamy,Sureshkumar, Purushothaman,Kanagarajan, Vijayakumar,Thanusu, Jeyaraman,Govindaraju, Ramalingam. "Silica gel supported sodium hydrogen sulfate as an efficient and reusable heterogeneous catalyst for the synthesis of imines in solvent-free conditions under microwave irradiation". . p. 299 - 303. Retrieved 2007/10/03.
• 2、 Abu-Eittah, Rafie Hassan,Hammed, Maher Mohamed. "Studies on the Electronic Absorption Spectra of Some Selected Furan Derivatives. Molecular Orbital Calculations". . p. 844 - 851. Retrieved 2007/10/02.