[2-(η6-cyclohepta-2,4,6-trienyl)phenyl]diphenylphosphane Mo(CO)2(P-Mo)

Base Information

• Chemical Name: [2-(η6-cyclohepta-2,4,6-trienyl)phenyl]diphenylphosphane Mo(CO)2(P-Mo)
• CAS No.: 442640-62-2
• Molecular Formula: C₂₇H₂₁MoO₂P
• Molecular Weight: 504.376
• Mol file: 442640-62-2.mol

Synonyms:

Chemical Property of [2-(η6-cyclohepta-2,4,6-trienyl)phenyl]diphenylphosphane Mo(CO)2(P-Mo)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [2-(η6-cyclohepta-2,4,6-trienyl)phenyl]diphenylphosphane Mo(CO)2(P-Mo)

There total 1 articles about [2-(η6-cyclohepta-2,4,6-trienyl)phenyl]diphenylphosphane Mo(CO)2(P-Mo) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

molybdenum hexacarbonyl (13939-06-5,199620-15-0) + [2-(cyclohepta-2,4,6-trienyl)phenyl]diphenylphosphane → [2-(η6-cyclohepta-2,4,6-trienyl)phenyl]diphenylphosphane Mo(CO)2(P-Mo) (442640-62-2)

Guidance literature:

In methyl cyclohexane; starting materials and solvent heated within 2 h to 120°C under Ar, and stirred for 10 h at this temp.; evapn. in vacuo, recrystn. (CH2Cl2/hexane at 0°C), after 12 h filtration; elem. anal.;

DOI:10.1002/1099-0682(200203)2002:4<918::AID-EJIC918>3.0.CO;2-E

Reference yield: 90.0%

[2-(η6-cyclohepta-2,4,6-trienyl)phenyl]diphenylphosphane Mo(CO)2(P-Mo) (442640-62-2) + trityl tetrafluoroborate (341-02-6) → [[2-(η7-cyclohepta-2,4,6-trienyl)phenyl]diphenylphosphane Mo(CO)2(P-Mo)]BF4

Guidance literature:

In dichloromethane; starting materials and solvent mixed at 0°C under Ar, then heatedto reflux for 30 min; solution reduced in volume by evapn., added to diethyl ether at 0°C, precipitate filtered and washed with diethyl ether, dried in vacuo; elem. anal.;

DOI:10.1002/1099-0682(200203)2002:4<918::AID-EJIC918>3.0.CO;2-E

upstream raw materials:

molybdenum hexacarbonyl