[Fe2(μ-CO)(μ-CC6H5)(CO)2(η-C5H5)2][BBr4]

Base Information

Chemical Name:[Fe2(μ-CO)(μ-CC6H5)(CO)2(η-C5H5)2][BBr4]
CAS No.:302352-26-7
Molecular Formula:BBr₄*C₂₀H₁₅Fe₂O₃
Molecular Weight:745.458
Hs Code.:

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Chemical Property of [Fe2(μ-CO)(μ-CC6H5)(CO)2(η-C5H5)2][BBr4]

Chemical Property:

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Technology Process of [Fe2(μ-CO)(μ-CC6H5)(CO)2(η-C5H5)2][BBr4]

There total 1 articles about [Fe2(μ-CO)(μ-CC6H5)(CO)2(η-C5H5)2][BBr4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: cis-{Cp2Fe2(CO)2(μ-CO)(μ-C(OEt)Ph)}

: 10294-33-4
boron tribromide

: 302352-26-7,300574-98-5
[Fe2(μ-CO)(μ-CC6H5)(CO)2(η-C5H5)2][BBr4]

Guidance literature:: In diethyl ether; under N2, to a soln. of complex in (CH3CH2)2O was added BBr3 at -65°C with vigorous stirring, the mixt. was stirred for 10 min; the mixt. was filtered, the solid was washed with (CH3CH2)2O at -65°C, dried under vac. at -40°C; elem. anal.;
DOI:10.1021/om000185i

Reference yield: 80.0%

: 302352-26-7,300574-98-5
[Fe2(μ-CO)(μ-CC6H5)(CO)2(η-C5H5)2][BBr4]

: Na[W(CO)5CN]

: [Fe2(.mu-CO)(μ-CPh)(CO)(η5-C5H5)2NCW(CO)5]*CH2Cl2

Guidance literature:: In tetrahydrofuran; dichloromethane; under N2 atm. to (Fe2(μ-CO)(μ-CPh)(CO)2(η5-C5H5)2)BBr4 in THFat -90°C was added Na(W(CO)5CN), react. mixt. was warmed slowly to -75°C within 1 h and additionally stirred at -75 to -30°C for 3 h; soln. was evapd. in vacuo at -30°C to dryness, residue was chromed. on Al2O3 at -25°C with petroleum ether/CH2Cl2 (10:1), solventwas removed under vac., residue was recrystd. from petroleum ether/CH2Cl2 at -80°c; elem. anal.;
DOI:10.1021/om0002529

Reference yield: 75.0%

: 302352-26-7,300574-98-5
[Fe2(μ-CO)(μ-CC6H5)(CO)2(η-C5H5)2][BBr4]

: Na⁽¹⁺⁾*Mo(CN)(CO)5^(1-) = Na[Mo(CN)(CO)5]

: [Fe2(.mu-CO)(μ-CPh)(CO)(η5-C5H5)2NCMo(CO)5]

Guidance literature:: In tetrahydrofuran; under N2 atm. to (Fe2(μ-CO)(μ-CPh)(CO)2(η5-C5H5)2)BBr4 in THFat -90°C was added Na(Mo(CO)5CN), react. mixt. was warmed slowlyto -75°C within 1 h and additionally stirred at -75 to -30°C for 3 h; soln. was evapd. in vacuo at -30°C to dryness, residue was chromed. on Al2O3 at -25°C with petroleum ether/CH2Cl2 (10:1), solventwas removed under vac., residue was recrystd. from petroleum ether/CH2Cl2 at -80°c; elem. anal.;
DOI:10.1021/om0002529