3-(trans-2'-(5',10',15',20'-tetraphenylporphyrinato zinc(II)yl))acrylic acid ethyl ester

Base Information

Chemical Name:3-(trans-2'-(5',10',15',20'-tetraphenylporphyrinato zinc(II)yl))acrylic acid ethyl ester
CAS No.:79299-65-3
Molecular Formula:C₄₉H₃₄N₄O₂Zn
Molecular Weight:776.225
Hs Code.:

Synonyms:

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Chemical Property of 3-(trans-2'-(5',10',15',20'-tetraphenylporphyrinato zinc(II)yl))acrylic acid ethyl ester

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Technology Process of 3-(trans-2'-(5',10',15',20'-tetraphenylporphyrinato zinc(II)yl))acrylic acid ethyl ester

There total 1 articles about 3-(trans-2'-(5',10',15',20'-tetraphenylporphyrinato zinc(II)yl))acrylic acid ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 3-trans-(5',10',15',20'-tetraphenylporphyrin-2'-yl)acrylic acid ethyl ester

: 5970-45-6
zinc(II) acetate dihydrate

: 79270-13-6,79299-65-3
3-(trans-2'-(5',10',15',20'-tetraphenylporphyrinato zinc(II)yl))acrylic acid ethyl ester

Guidance literature:: In methanol; chloroform; shielded from ambient light; soln. of Zn(OAc)2*2H2O in MeOH added to soln. of porphyrin in CHCl3 with stirring at room temp. under N2; reaction completed after 30 min (monitoring by TLC); solvent removed in vac.; column chromy. (silica/CH2Cl2-hexane (2:1)), major band;
DOI:10.1021/jp052877w

Reference yield: 100.0%

: 79270-13-6,79299-65-3
3-(trans-2'-(5',10',15',20'-tetraphenylporphyrinato zinc(II)yl))acrylic acid ethyl ester

: 7732-18-5
water

: 3-(trans-2'-(5',10',15',20'-tetraphenylporphyrinato zinc(II)yl))acrylic acid

Guidance literature:: With NaOH; In tetrahydrofuran; ethanol; water; shielded from ambient light; aq. soln. of NaOH added to refluxing soln. of Zn complex in THF and EtOH under N2; reaction completed after 90 min (monitoring by TLC); cooled to room temp.; CH2Cl2, H2O, Et2O, and 2 M aq. H3PO4 added; shaken (pH 2.5), sepn.; org. layer rinsed with H2O and few ml 2 M H3PO4; sepn.; dried (MgSO4); removal of solvent in vac., dissolved in warm acetone and THF, filtered; pptn. with H2O with 4 drops CH3COOH; rinsed with acetone/H2O;
DOI:10.1021/jp052877w