trans-[ruthenium(II) hydride (PF₃) bis[1,2-bis(diphenylphosphanyl)methane]] tetrafluoroborate

Base Information

• Chemical Name: trans-[ruthenium(II) hydride (PF₃) bis[1,2-bis(diphenylphosphanyl)methane]] tetrafluoroborate
• CAS No.: 823786-34-1
• Molecular Formula: BF₄*C₅₀H₄₅F₃P₅Ru
• Molecular Weight: 1045.65
• Mol file: 823786-34-1.mol

Synonyms:

Chemical Property of trans-[ruthenium(II) hydride (PF₃) bis[1,2-bis(diphenylphosphanyl)methane]] tetrafluoroborate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of trans-[ruthenium(II) hydride (PF₃) bis[1,2-bis(diphenylphosphanyl)methane]] tetrafluoroborate

There total 1 articles about trans-[ruthenium(II) hydride (PF₃) bis[1,2-bis(diphenylphosphanyl)methane]] tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

trans-[ruthenium(II) hydride (η2-dihydrogen)bis[1,2-bis(diphenylphosphanyl)methane]] tetrafluoroborate + trifluorophosphane (7783-55-3) → trans-[ruthenium(II) hydride (PF3) bis[1,2-bis(diphenylphosphanyl)methane]] tetrafluoroborate (823786-34-1)

Guidance literature:

In dichloromethane; (H2), Ru complex in CH2Cl2 treated with PF3 gas for 10 min, stirred at room temp. for 2 h; concd., pptd.(Et2O), dried (vac.), recrystd.(CH2Cl2/Et2O) for several d;

DOI:10.1002/ejic.200400130

Reference yield:

[D3]acetonitrile (2206-26-0) + trans-[ruthenium(II) hydride (PF3) bis[1,2-bis(diphenylphosphanyl)methane]] tetrafluoroborate (823786-34-1) → trans-[ruthenium(II)(CD3CN) (PF3) bis[1,2-bis(diphenylphosphanyl)methane]]

Guidance literature:

In dichloromethane-d2; protonated in CD2Cl2, treated with CD3CN; not isolated, detected by NMR;

DOI:10.1002/ejic.200400130

Reference yield:

trans-[ruthenium(II) hydride (PF3) bis[1,2-bis(diphenylphosphanyl)methane]] tetrafluoroborate (823786-34-1) + trifluorormethanesulfonic acid (1493-13-6) → trans-[ruthenium(II)(η2-dihydrogen) (PF3) bis[1,2-bis(diphenylphosphanyl)methane]] + cis-[ruthenium(II)(η2-dihydrogen) (PF3) bis[1,2-bis(diphenylphosphanyl)methane]]

Guidance literature:

In dichloromethane; Ru complex in NMR tube evacuated, filled (H2), dissolved (CH2Cl2), cooled (liquid N2), treated with triflic acid, warmed to 273 K; not isolated, detected by NMR;

DOI:10.1002/ejic.200400130

upstream raw materials:

trifluorophosphane